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Influence of extrusion, stretching and poling on the structural and piezoelectric properties of poly (vinylidene fluoride-hexafluoropropylene) copolymer films

文献类型:期刊论文

作者Huan, Yan; Liu, Yayan; Yang, Yifei; Wu, Yanan
刊名Journal of applied polymer science
出版日期2007-04-15
卷号104期号:2页码:858-862
关键词Pvdf-hfp Pvdf poling Extrusion Stretching Piezoelectricity
ISSN号0021-8995
DOI10.1002/app.25603
通讯作者Liu, yayan(yyliu@ciac.jl.cn)
英文摘要Three types of poly (vinylidene fluoride-hexafluoropropylene) (pvdf-hfp) copolymer films were prepared by extrusion, stretching as well as simultaneously stretching and static electric field poling (sssep), respectively, and measured by the differential scanning calorimetric, wide angle x-ray diffraction, fourier transformation infrared-attenuated total reflection, and dynamic mechanical analysis. the experimental results showed that the films prepared by stretching and sssep have higher crystallinity and phase than by extrusion. sssep improved the chain orientation enormously both in crystalline and amorphous regions, resulting in the highest storage modulus. because of the lower p phase content, the extruded films exhibited the lowest piezoelectric coefficient d(33). for the stretched and sssep films, although the p phase content was similar, the d(33) was distinct because of the different potential energy for the rotation of the dipoles. in addition, the sssep films gave the maximum d(33) (24 pc/n), higher than the other pvdf-hfp copolymer films that have been reported. (c) 2007 wiley periodicals, inc.
WOS关键词POLY(VINYLIDENE FLUORIDE-TRIFLUOROETHYLENE) COPOLYMER ; RELAXOR FERROELECTRIC BEHAVIOR ; CRYSTALLINE PHASES ; PVDF FILMS ; TRANSITIONS ; ELECTROSTRICTION ; ELECTROLYTES ; SPECTROSCOPY ; TEMPERATURE ; MORPHOLOGY
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000244587000024
出版者JOHN WILEY & SONS INC
URI标识http://www.irgrid.ac.cn/handle/1471x/2382197
专题中国科学院大学
通讯作者Liu, Yayan
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, Green Chem & Proc Lab, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Jilin Univ, Changchun 5988, Peoples R China
推荐引用方式
GB/T 7714
Huan, Yan,Liu, Yayan,Yang, Yifei,et al. Influence of extrusion, stretching and poling on the structural and piezoelectric properties of poly (vinylidene fluoride-hexafluoropropylene) copolymer films[J]. Journal of applied polymer science,2007,104(2):858-862.
APA Huan, Yan,Liu, Yayan,Yang, Yifei,&Wu, Yanan.(2007).Influence of extrusion, stretching and poling on the structural and piezoelectric properties of poly (vinylidene fluoride-hexafluoropropylene) copolymer films.Journal of applied polymer science,104(2),858-862.
MLA Huan, Yan,et al."Influence of extrusion, stretching and poling on the structural and piezoelectric properties of poly (vinylidene fluoride-hexafluoropropylene) copolymer films".Journal of applied polymer science 104.2(2007):858-862.

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来源:中国科学院大学

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