Tio2 porous electrodes with hierarchical branched inner channels for charge transport in viscous electrolytes
文献类型：期刊论文
| 作者 | Zhao, Yong; Sheng, Xianliang; Zhai, Jin; Jiang, Lei; Yang, Chunhe; Sun, Zhongwei; Li, Yongfang; Zhu, Daoben |
| 刊名 | Chemphyschem
 |
| 出版日期 | 2007-04-23 |
| 卷号 | 8期号:6页码:856-861 |
| 关键词 | Charge transport Dyes/pigments Electrochemistry Light harvesting Nanostructures |
| ISSN号 | 1439-4235 |
| DOI | 10.1002/cphc.200600664 |
| 通讯作者 | Zhai, jin(zhaijin@iccas.ac.cn) |
| 英文摘要 | Titanium dioxide (tio2) photoelectrodes with micro/nano heirarchical branched inner channels have been prepared by an electrohydrodynamic (ehd) technique and assembled to form dye-sensitized solar cells (dsscs). excellent penetration of ionic-liquid electrolytes and enhanced light harvesting in the longer wave-length region are realized within the composite-structure electrode, thus a better fill factor (ff) of 75.3% and higher conversion efficiency (eta) of 7.1% are obtained for viscous ionic-liquid electrolytes compared to pure nanostructured films. hierarchical branced channels in the photoanodes can efficiently improve the transport properties of redox-active species in viscous electrolytes, which is demonstrated by electric impedance spectroscopy (eis). the incident monochromatic photon-to-electron conversion efficiency (ipce) shows that enhanced light scaterring in the composite film is of benefit for light harvesting and thus for solar energy conversion efficiency. |
| WOS关键词 | SENSITIZED SOLAR-CELLS ; NANOCRYSTALLINE TIO2 ; IONIC LIQUID ; DYE ; FILMS ; EFFICIENCY ; CONVERSION ; PHOTOCURRENT ; ENHANCEMENT ; PERFORMANCE |
| WOS研究方向 | Chemistry ; Physics |
| WOS类目 | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000246190900009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2382236 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhai, Jin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yong,Sheng, Xianliang,Zhai, Jin,et al. Tio2 porous electrodes with hierarchical branched inner channels for charge transport in viscous electrolytes[J]. Chemphyschem,2007,8(6):856-861. |
| APA | Zhao, Yong.,Sheng, Xianliang.,Zhai, Jin.,Jiang, Lei.,Yang, Chunhe.,...&Zhu, Daoben.(2007).Tio2 porous electrodes with hierarchical branched inner channels for charge transport in viscous electrolytes.Chemphyschem,8(6),856-861. |
| MLA | Zhao, Yong,et al."Tio2 porous electrodes with hierarchical branched inner channels for charge transport in viscous electrolytes".Chemphyschem 8.6(2007):856-861. |
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来源：中国科学院大学
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