Effect of the Reduction Temperature of Co-La-Zr/AC on the Synthesis of Higher Alcohols from Syngas
文献类型:期刊论文
作者 | Jiao Guiping1,2; Ding Yunjie1; Zhu Hejun; Li Xianming2; Dong Wenda2; Li Jingwei2; Lue Yuan |
刊名 | chinese journal of catalysis
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出版日期 | 2009-02-01 |
卷号 | 30期号:2页码:92-94 |
关键词 | cobalt catalyst Fischer-Tropsch synthesis reduction temperature higher alcohol cobalt carbide |
产权排序 | 1;1 |
通讯作者 | 丁云杰 |
英文摘要 | co hydrogenation over a co-la-zr/ac catalyst prepared by co-impregnation and reduced at different temperatures was studied. the catalyst reduced at 703 k showed good activity at 3.0 mpa, 495 k, h(2)-/co(v/v) = 2, and ghsv = 500 h(-1). co conversion and selectivity for total alcohols were 59.1% and 42.0%, respectively, and c(6)-c(18) higher alcohols were 50.4% of the alcohols. metallic cobalt and cobalt carbide were detected by xrd as the main cobalt species. the reduction temperature affects both the cobalt dispersion and formation of cobalt carbide. cobalt carbide may play an important role in the synthesis of higher alcohols on co-la-zr/ac. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | cobalt catalysts |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000264168700004 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/101953] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Liaoning 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Jiao Guiping,Ding Yunjie,Zhu Hejun,et al. Effect of the Reduction Temperature of Co-La-Zr/AC on the Synthesis of Higher Alcohols from Syngas[J]. chinese journal of catalysis,2009,30(2):92-94. |
APA | Jiao Guiping.,Ding Yunjie.,Zhu Hejun.,Li Xianming.,Dong Wenda.,...&Lue Yuan.(2009).Effect of the Reduction Temperature of Co-La-Zr/AC on the Synthesis of Higher Alcohols from Syngas.chinese journal of catalysis,30(2),92-94. |
MLA | Jiao Guiping,et al."Effect of the Reduction Temperature of Co-La-Zr/AC on the Synthesis of Higher Alcohols from Syngas".chinese journal of catalysis 30.2(2009):92-94. |
入库方式: OAI收割
来源:大连化学物理研究所
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