Effect of ball milling time on the hydrogen storage properties of TiF3-doped LiAlH4
文献类型：期刊论文
| 作者 | Liu, Shu-Sheng1,3; Sun, Li-Xian1; Zhang, Yao1; Xu, Fen2; Zhang, Jian1; Chu, Hai-Liang1; Fan, Mei-Qiang1; Zhang, Tao1; Song, Xiao-Yan4; Grolier, Jean Pierre5 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2009-10-01 |
| 卷号 | 34期号:19页码:8079-8085 |
| 关键词 | Hydrogen storage TiF3 LiAlH4 Ball milling time |
| 产权排序 | 1;1 |
| 通讯作者 | 孙立贤 |
| 英文摘要 | in the present work, the catalytic effect of tif3 on the dehydrogenation properties of lialh4 has been investigated. decomposition of lialh4 occurs during ball milling in the presence of 4 mol% tif3. different ball milling times have been used, from 0.5 h to 18 h. with ball milling time increasing, the crystallite sizes of lialh4 get smaller (from 69 nm to 43 nm) and the dehydrogenation temperature becomes lower (from 80 degrees c to 60 degrees c). half an hour ball milling makes the initial dehydrogenation temperature of doped lialh4 reduce to 80 degrees c, which is 70 degrees c lower than as-received lialh4. about 5.0 wt.% h-2 can be released from tif3-doped lialh4 after 18 h ball milling in the range of 60 degrees c-145 degrees c (heating rate 2 degrees c min(-1)). tif3 probably reacts with lialh4 to form the catalyst, tial3. the mechanochemical and thermochemical reactions have been clarified. however, the rehydrogenation of lialh4/li3alh6 can not be realized under 95 bar h-2 in the presence of tif3 because of their thermodynamic properties. (c) 2009 professor t. nejat veziroglu. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | lithium aluminum-hydride ; metal hydrides ; alanate lialh4 ; release ; naalh4 ; stability ; catalysts ; tif3 ; transformations ; decomposition |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000271354700025 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101985]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Liaoning, Peoples R China 2.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Chinese Educ Minist, Beijing 100124, Peoples R China 5.Univ Clermont Ferrand, Lab Thermodynam Solut & Polymers, F-63177 Aubiere, France |
| 推荐引用方式 GB/T 7714 | Liu, Shu-Sheng,Sun, Li-Xian,Zhang, Yao,et al. Effect of ball milling time on the hydrogen storage properties of TiF3-doped LiAlH4[J]. international journal of hydrogen energy,2009,34(19):8079-8085. |
| APA | Liu, Shu-Sheng.,Sun, Li-Xian.,Zhang, Yao.,Xu, Fen.,Zhang, Jian.,...&Grolier, Jean Pierre.(2009).Effect of ball milling time on the hydrogen storage properties of TiF3-doped LiAlH4.international journal of hydrogen energy,34(19),8079-8085. |
| MLA | Liu, Shu-Sheng,et al."Effect of ball milling time on the hydrogen storage properties of TiF3-doped LiAlH4".international journal of hydrogen energy 34.19(2009):8079-8085. |
入库方式： OAI收割
来源：大连化学物理研究所
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