Synthesis of cyanated tetracenes as the organic semiconductors
文献类型：期刊论文
| 作者 | Li, An1; Wen, Shu-Hao1,2; Song, Jun-Ling1; Deng, Wei-Qiao1,2 |
| 刊名 | organic electronics
 |
| 出版日期 | 2009-09-01 |
| 卷号 | 10期号:6页码:1054-1059 |
| 关键词 | Organic semiconductor Hole mobility Reorganization energy Cyanated tetracene Air-stable |
| 产权排序 | 2;2 |
| 通讯作者 | 邓伟侨 |
| 英文摘要 | two novel and air-stable cyanated tetracene derivatives, 5-cyanotetracene (1ct) and 5,11-dicyanotetracene (2ct), were synthesized as high-performance organic semiconductors. the stability of 2ct was evaluated by nmr and the electrochemical property was investigated by cyclic voltammetry (cv) and uv-vis spectrum. the reorganization energy of 2ct predicted by ub3lyp/6-311g(d,p) is 0.0881 ev, which is the lowest among existing compounds. the x-ray crystallographic analysis revealed that the 2ct single crystal has a promising face-to-face packing with a relative short intermolecular distance of 3.403 angstrom. based on the theoretical model we previously developed, the calculated hole mobilities of these air-stable cyanated tetracene derivatives in a-b plane are 2.9 cm(2) v-1 s(-1) for 1ct and 2.2 cm(2) v-1 s(-1) for 2ct, respectively. these oxygen-resisted organics may offer potential to fabricate the flexible electronics under air conditions. crown copyright (c) 2009 published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | materials science, multidisciplinary ; physics, applied |
| 研究领域[WOS] | materials science ; physics |
| 关键词[WOS] | field-effect transistors ; charge-transport ; packing ; performance ; mobilities ; oligomers ; energies |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000269279200003 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102027]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637616, Singapore 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, An,Wen, Shu-Hao,Song, Jun-Ling,et al. Synthesis of cyanated tetracenes as the organic semiconductors[J]. organic electronics,2009,10(6):1054-1059. |
| APA | Li, An,Wen, Shu-Hao,Song, Jun-Ling,&Deng, Wei-Qiao.(2009).Synthesis of cyanated tetracenes as the organic semiconductors.organic electronics,10(6),1054-1059. |
| MLA | Li, An,et al."Synthesis of cyanated tetracenes as the organic semiconductors".organic electronics 10.6(2009):1054-1059. |
入库方式： OAI收割
来源：大连化学物理研究所
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