An efficient synthesis of resveratrol and a hydroxyl derivative via the perkin reaction: cis to trans isomerisation in a demethylation process
文献类型:期刊论文
作者 | Li, Guoxing1,2; Zou, Yong1; Zhang, Xuejing1 |
刊名 | Journal of chemical research
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出版日期 | 2007-11-01 |
期号 | 11页码:657-659 |
关键词 | Polyphenolic stilbenes Perkin reaction Resveratrol 3,4,4 ',5-trans-tetrahydroxystilbene Isomerisation |
ISSN号 | 1747-5198 |
DOI | 10.3184/030823407x266234 |
通讯作者 | Zou, yong(zou_jinan@163.com) |
英文摘要 | Two trans polyphenolic stilbenes, resveratrol and 3,4,4',5-trans-tetrahydroxystilbene, were prepared in three steps from 4-methoxy phenylacetic acid and methoxylated benzaldehydes via a perkin reaction. an interesting cis to trans isomerisation occured in the demethylation process in the presence of aii(3) and acetonitrile to give resveratrol and 3,4,4',5-trans-tetrahydroxystilbene with overall yields of 51% and 48% respectively. |
WOS关键词 | ANALOG ; CELLS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000254178200013 |
出版者 | SCIENCE REVIEWS 2000 LTD |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2382752 |
专题 | 中国科学院大学 |
通讯作者 | Zou, Yong |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Guangzhou 510650, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Guoxing,Zou, Yong,Zhang, Xuejing. An efficient synthesis of resveratrol and a hydroxyl derivative via the perkin reaction: cis to trans isomerisation in a demethylation process[J]. Journal of chemical research,2007(11):657-659. |
APA | Li, Guoxing,Zou, Yong,&Zhang, Xuejing.(2007).An efficient synthesis of resveratrol and a hydroxyl derivative via the perkin reaction: cis to trans isomerisation in a demethylation process.Journal of chemical research(11),657-659. |
MLA | Li, Guoxing,et al."An efficient synthesis of resveratrol and a hydroxyl derivative via the perkin reaction: cis to trans isomerisation in a demethylation process".Journal of chemical research .11(2007):657-659. |
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来源:中国科学院大学
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