中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves

文献类型:期刊论文

作者Xu, Haolan; Wang, Wenzhong; Zhu, Wei; Zhou, Lin; Ruan, Meilin
刊名Crystal growth & design
出版日期2007-12-01
卷号7期号:12页码:2720-2724
ISSN号1528-7483
DOI10.1021/cg060727k
通讯作者Wang, wenzhong(wzwang@mail.sic.ac.cn)
英文摘要One-dimensional (1d) cu(oh)(2) nanowires are converted into to two-dimensional (2d) cuo nanoleaves on a large scale, in which hierarchical-oriented attachment is involved. the whole transition process is captured and studied with the assistance of transmission electron microscopy (tem) and high-resolution tem images. polycrystalline cu(oh)(2) nanowires first evolved into single crystalline cu(oh)(2) nanoleaves by an oriented attachment. in this process, cu(oh)(2) nanoparticles (about 3 nm in diameter), which constructed the cu(oh)(2) nanowires, rotated, oriented, and attached to produce single crystalline cu(oh)(2) nanoleaves. then, these single crystalline cu(oh)(2) nanoleaves converted into single crystalline cuo nanoleaves via a reconstructive transformation, which consisted of the nucleation of cuo followed by a two-step oriented attachment of the cuo particles. in the formation of cuo nanoleaves, when the highest energy surfaces were eliminated by oriented attachment (from zero-dimensional nanoparticles to id nanoribbons), the subordinate high-energy surfaces became the highest one, and the oriented attachment took place sequentially on these subordinate surfaces (from 1d nanoribbons to 2d nanoleaves). the attached particles with angles caused by the unfinished rotation of nanoparticles in the formation of single crystalline nanoleaves, which was supposed to be a necessary process for oriented attachment, were observed under the experimental conditions. this revealed the potentiality for the formation of 2d or three-dimensional nanostructures by hierarchical-oriented attachment. these findings may be helpful for understanding the nanocrystal growth process and the oriented attachment mechanism in depth.
WOS关键词CRYSTAL-GROWTH ; NANORODS ; ZNO ; NANOPARTICLES ; ROUTE
WOS研究方向Chemistry ; Crystallography ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000251473200058
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2383053
专题中国科学院大学
通讯作者Wang, Wenzhong
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Xu, Haolan,Wang, Wenzhong,Zhu, Wei,et al. Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves[J]. Crystal growth & design,2007,7(12):2720-2724.
APA Xu, Haolan,Wang, Wenzhong,Zhu, Wei,Zhou, Lin,&Ruan, Meilin.(2007).Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves.Crystal growth & design,7(12),2720-2724.
MLA Xu, Haolan,et al."Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves".Crystal growth & design 7.12(2007):2720-2724.

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来源:中国科学院大学

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