Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves
文献类型:期刊论文
作者 | Xu, Haolan; Wang, Wenzhong; Zhu, Wei; Zhou, Lin; Ruan, Meilin |
刊名 | Crystal growth & design
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出版日期 | 2007-12-01 |
卷号 | 7期号:12页码:2720-2724 |
ISSN号 | 1528-7483 |
DOI | 10.1021/cg060727k |
通讯作者 | Wang, wenzhong(wzwang@mail.sic.ac.cn) |
英文摘要 | One-dimensional (1d) cu(oh)(2) nanowires are converted into to two-dimensional (2d) cuo nanoleaves on a large scale, in which hierarchical-oriented attachment is involved. the whole transition process is captured and studied with the assistance of transmission electron microscopy (tem) and high-resolution tem images. polycrystalline cu(oh)(2) nanowires first evolved into single crystalline cu(oh)(2) nanoleaves by an oriented attachment. in this process, cu(oh)(2) nanoparticles (about 3 nm in diameter), which constructed the cu(oh)(2) nanowires, rotated, oriented, and attached to produce single crystalline cu(oh)(2) nanoleaves. then, these single crystalline cu(oh)(2) nanoleaves converted into single crystalline cuo nanoleaves via a reconstructive transformation, which consisted of the nucleation of cuo followed by a two-step oriented attachment of the cuo particles. in the formation of cuo nanoleaves, when the highest energy surfaces were eliminated by oriented attachment (from zero-dimensional nanoparticles to id nanoribbons), the subordinate high-energy surfaces became the highest one, and the oriented attachment took place sequentially on these subordinate surfaces (from 1d nanoribbons to 2d nanoleaves). the attached particles with angles caused by the unfinished rotation of nanoparticles in the formation of single crystalline nanoleaves, which was supposed to be a necessary process for oriented attachment, were observed under the experimental conditions. this revealed the potentiality for the formation of 2d or three-dimensional nanostructures by hierarchical-oriented attachment. these findings may be helpful for understanding the nanocrystal growth process and the oriented attachment mechanism in depth. |
WOS关键词 | CRYSTAL-GROWTH ; NANORODS ; ZNO ; NANOPARTICLES ; ROUTE |
WOS研究方向 | Chemistry ; Crystallography ; Materials Science |
WOS类目 | Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000251473200058 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383053 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Wenzhong |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Haolan,Wang, Wenzhong,Zhu, Wei,et al. Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves[J]. Crystal growth & design,2007,7(12):2720-2724. |
APA | Xu, Haolan,Wang, Wenzhong,Zhu, Wei,Zhou, Lin,&Ruan, Meilin.(2007).Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves.Crystal growth & design,7(12),2720-2724. |
MLA | Xu, Haolan,et al."Hierarchical-oriented attachment: from one-dimensional cu(oh)(2) nanowires to two-dimensional cuo nanoleaves".Crystal growth & design 7.12(2007):2720-2724. |
入库方式: iSwitch采集
来源:中国科学院大学
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