Rhodium-catalyzed reaction of diazoacetates, thiols and azodicarboxylates: an unusual 1,2-aza shift from a sulfonium ylide
文献类型：期刊论文
| 作者 | Huang, Haoxi; Hu, Wenhao |
| 刊名 | Synlett
 |
| 出版日期 | 2007-05-16 |
| 期号 | 8页码:1314-1316 |
| 关键词 | One-pot reaction Diazo compounds Sulfonium ylides N,s-ketals Rearrangement reaction |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-2007-977454 |
| 通讯作者 | Hu, wenhao(whu@chem.ecnu.edu.cn) |
| 英文摘要 | A one-pot reaction of diazoacetates, thiols and azodicarboxylates in the presence of a dirbodium acetate catalyst gave n,s-ketals in good yields. this reaction proceeded via an unusual 1,2-aza shift from a sulfonium ylide intermediate. |
| WOS关键词 | CARBENOID MEDIATED CYCLIZATIONS ; 3-COMPONENT REACTION ; ORGANIC-SYNTHESIS ; DIAZO-COMPOUNDS ; REARRANGEMENT ; ALDEHYDES ; METHYLIDE ; ACETATE ; ESTERS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000247217700031 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383064 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Hu, Wenhao |
| 作者单位 | 1.E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Haoxi,Hu, Wenhao. Rhodium-catalyzed reaction of diazoacetates, thiols and azodicarboxylates: an unusual 1,2-aza shift from a sulfonium ylide[J]. Synlett,2007(8):1314-1316. |
| APA | Huang, Haoxi,&Hu, Wenhao.(2007).Rhodium-catalyzed reaction of diazoacetates, thiols and azodicarboxylates: an unusual 1,2-aza shift from a sulfonium ylide.Synlett(8),1314-1316. |
| MLA | Huang, Haoxi,et al."Rhodium-catalyzed reaction of diazoacetates, thiols and azodicarboxylates: an unusual 1,2-aza shift from a sulfonium ylide".Synlett .8(2007):1314-1316. |
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来源：中国科学院大学
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