Low-temperature flux syntheses and characterizations of two 1-d anhydrous borophosphates: na3b6po13 and na3bp2o8
文献类型：期刊论文
| 作者 | Xiong, Ding-Bang; Chen, Hao-Hong; Yang, Xin-Xin; Zhao, Jing-Tai |
| 刊名 | Journal of solid state chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 180期号:1页码:233-239 |
| 关键词 | Crystal structure Borophosphate Flux synthesis |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2006.09.034 |
| 通讯作者 | Zhao, jing-tai(jtzhao@mail.sic.ac.cn) |
| 英文摘要 | Two new anhydrous sodium borophosphates with one-dimensional structure, na3b6po13 (1) and na3bp2o8 (2), were synthesized by low-temperature inolten salts techniques using boric acid and sodium dihydrogen phosphate as flux, respectively. the crystal structures were solved by means of single-crystal x-ray diffraction (1, orthorhombic, pnma (no. 62), a = 9.3727(4) angstrom, b = 16.2307(7) angstrom, c = 6.7232(3) angstrom, z = 4; 2, monoclinic, c2/c (no. 15), a = 12.567(4) angstrom, b = 10.290(3) angstrom, c = 10.210(3) angstrom, beta = 92.492(5)degrees, z = 8). compound 1 is characterized by an infinite chain of (1)(infinity){[b6po13]}(3-) containing eight-membered rings in which all vertexes of borate groups contribute to interconnection. compound 2 reveals an infinite straight chain (1)(infinity){[bp2o8]}(3-) built of vertex-sharing four-membered rings, and chains in neighboring layers arranged along different orientations. the relations between structures and the synthetic conditions with only traced water are discussed. (c) 2006 elsevier inc. all rights reserved. |
| WOS关键词 | CRYSTAL-STRUCTURE ; BORIC-ACID ; BORATE POLYMER ; FRAMEWORK ; SOLIDS ; ZN ; MN ; FE ; NI |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000243951900032 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383231 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhao, Jing-Tai |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Ding-Bang,Chen, Hao-Hong,Yang, Xin-Xin,et al. Low-temperature flux syntheses and characterizations of two 1-d anhydrous borophosphates: na3b6po13 and na3bp2o8[J]. Journal of solid state chemistry,2007,180(1):233-239. |
| APA | Xiong, Ding-Bang,Chen, Hao-Hong,Yang, Xin-Xin,&Zhao, Jing-Tai.(2007).Low-temperature flux syntheses and characterizations of two 1-d anhydrous borophosphates: na3b6po13 and na3bp2o8.Journal of solid state chemistry,180(1),233-239. |
| MLA | Xiong, Ding-Bang,et al."Low-temperature flux syntheses and characterizations of two 1-d anhydrous borophosphates: na3b6po13 and na3bp2o8".Journal of solid state chemistry 180.1(2007):233-239. |
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来源：中国科学院大学
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