Synthesis and crystal structure of a 2-d hydrogen-bonded supramolecular network {[cu-4(oh)(4)(2,2 '-bpy)(4)(bqdc)]center dot 2clo(4)}n
文献类型：期刊论文
| 作者 | Luo Jun-Hua; Lian, Chen; Yue Cheng-Yang; Jiang Fei-Long; Hong Mao-Chun |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:6页码:654-658 |
| 关键词 | Hydrothermal method Copper(ii) Crystal structure Supramolecular |
| ISSN号 | 0254-5861 |
| 通讯作者 | Jiang fei-long(fjiang@fjirsm.ac.cn) |
| 英文摘要 | The title compound {[cu-4(oh)(4)(2,2'-bpy)(4)(bqdc)]center dot 2clo(4)}(n) 1(bqdc = 2,2'-biquinoline-4,4'-dicarboxylic acid) has been synthesized by hydrothermal method. its crystal structure is of triclinic, space group p (1) over bar with a = 7.6561(5), b = 12-4652(8), c = 15.7501(10) angstrom, alpha = 80.0480(10), beta = 87.7900(10), gamma = 74.0800(1)degrees, v = 1423.65(16) angstrom(3), z = 2, c30h23cln5o8cu2, m-r = 744.06, d-c = 1.736 g/cm(3), mu = 1.651 mm(-1), f(000) = 754, the final r = 0.0421 and wr = 0.1163 for 4973 observed reflections with i > 2 sigma(i). in 1, tetra-copper chair-like clusters of [cu-4(oh)(4)(2,2'-bpy)(4)](4+) are connected by bqdc ligands to form one-dimensional chains, which are further connected by hydrogen bonds to generate a two-dimensional supramolecular network. |
| WOS关键词 | PI-PI STACKING ; COMPLEXES ; ARCHITECTURES ; LIGANDS |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000247676400006 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383268 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Jiang Fei-Long |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo Jun-Hua,Lian, Chen,Yue Cheng-Yang,et al. Synthesis and crystal structure of a 2-d hydrogen-bonded supramolecular network {[cu-4(oh)(4)(2,2 '-bpy)(4)(bqdc)]center dot 2clo(4)}n[J]. Chinese journal of structural chemistry,2007,26(6):654-658. |
| APA | Luo Jun-Hua,Lian, Chen,Yue Cheng-Yang,Jiang Fei-Long,&Hong Mao-Chun.(2007).Synthesis and crystal structure of a 2-d hydrogen-bonded supramolecular network {[cu-4(oh)(4)(2,2 '-bpy)(4)(bqdc)]center dot 2clo(4)}n.Chinese journal of structural chemistry,26(6),654-658. |
| MLA | Luo Jun-Hua,et al."Synthesis and crystal structure of a 2-d hydrogen-bonded supramolecular network {[cu-4(oh)(4)(2,2 '-bpy)(4)(bqdc)]center dot 2clo(4)}n".Chinese journal of structural chemistry 26.6(2007):654-658. |
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来源：中国科学院大学
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