Changes in the surfaces of adsorbed para-nitrophenol on hdtma organoclay- the xrd and tg study
文献类型:期刊论文
作者 | Zhou, Qin; Frost, Ray L.; He, Hongping; Xi, Yunfei |
刊名 | Journal of colloid and interface science
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出版日期 | 2007-03-01 |
卷号 | 307期号:1页码:50-55 |
关键词 | Montmorillonite Organoclay Surfactant High resolution thermogravimetric analysis X-ray diffraction |
ISSN号 | 0021-9797 |
DOI | 10.1016/j.jcis.2006.11.016 |
通讯作者 | Frost, ray l.(r.frost@qut.edu.au) |
英文摘要 | Surfactant modified montmorillonitic clays synthesized by ion exchange using the hydrothermal reaction method have been compared using xrd and thermal analysis. x-ray diffraction (xrd) shows the changes in the surface properties of organoclays through expansion with surfactant loading. a polynomial relationship exists between the basal spacing and the cec loading described by the equation y = 0.3232x(2) + 0.2052x + 1.2834 with r(2) = 0.9955. different arrangements of the surfactant molecules in the organoclays are inferred from the changes in basal spacings. para-nitrophenol also causes the expansion of the montmorillonite clay and affects the arrangements of the surfactant molecules within the clay layers. changes in the surfactant molecular arrangements were analyzed by thermogravimetry. additional thermal decomposition steps were observed when para-nitrophenol is adsorbed on the organoclay. (c) 2006 elsevier inc. all rights reserved. |
WOS关键词 | SORPTION ; MONTMORILLONITE ; INTERLAYER ; BEHAVIOR ; CATIONS ; PHENOL ; ACID |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
WOS记录号 | WOS:000243570400008 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383273 |
专题 | 中国科学院大学 |
通讯作者 | Frost, Ray L. |
作者单位 | 1.Queensland Univ Technol, Sch Phys & Chem Sci, Inorgan Mat Res Program, Brisbane, Qld 4001, Australia 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 4.Univ S Australia, Ctr Environm Risk Assessment & Remediat, Mawson Lakes, SA 5095, Australia |
推荐引用方式 GB/T 7714 | Zhou, Qin,Frost, Ray L.,He, Hongping,et al. Changes in the surfaces of adsorbed para-nitrophenol on hdtma organoclay- the xrd and tg study[J]. Journal of colloid and interface science,2007,307(1):50-55. |
APA | Zhou, Qin,Frost, Ray L.,He, Hongping,&Xi, Yunfei.(2007).Changes in the surfaces of adsorbed para-nitrophenol on hdtma organoclay- the xrd and tg study.Journal of colloid and interface science,307(1),50-55. |
MLA | Zhou, Qin,et al."Changes in the surfaces of adsorbed para-nitrophenol on hdtma organoclay- the xrd and tg study".Journal of colloid and interface science 307.1(2007):50-55. |
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来源:中国科学院大学
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