MgO-supported Cu nanoparticles for efficient transfer dehydrogenation of primary aliphatic alcohols
文献类型：期刊论文
| 作者 | Shi, Ruijuan; Wang, Fei; Mu, Xiaoling; Li, Yong; Huang, Xiumin; Shen, Wenjie |
| 刊名 | catalysis communications
 |
| 出版日期 | 2009-12-15 |
| 卷号 | 11期号:4页码:306-309 |
| 关键词 | Transfer dehydrogenation Primary aliphatic alcohols Aldehydes Cu/MgO Basicity |
| 通讯作者 | 申文杰 |
| 产权排序 | 1;1 |
| 英文摘要 | basic mgo-supported cu nanoparticles showed exceptionally high activity for transfer dehydrogenation of 1-octanol and the yield of 1-octanal was as high as 58% at 423 k. the cu/mgo catalyst was also sufficiently active for aromatic, secondary aliphatic and cyclic alcohols, and the yields of the corresponding aldehydes or ketones approached almost 100%. structure-reactivity correlation revealed that the synergistic effect between the basicity of mgo and the hydrogen spillover of cu nanoparticle contributed significantly to the extremely high activity in transfer dehydrogenation of alcohols. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | environmentally benign oxidation ; ruthenium catalyst ; hydrotalcite ; palladium ; cu/al2o3 ; acceptor ; surface ; oxides ; oxygen |
| 收录类别 | SCI ; CCR |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000272979900018 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102223]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Ruijuan,Wang, Fei,Mu, Xiaoling,et al. MgO-supported Cu nanoparticles for efficient transfer dehydrogenation of primary aliphatic alcohols[J]. catalysis communications,2009,11(4):306-309. |
| APA | Shi, Ruijuan,Wang, Fei,Mu, Xiaoling,Li, Yong,Huang, Xiumin,&Shen, Wenjie.(2009).MgO-supported Cu nanoparticles for efficient transfer dehydrogenation of primary aliphatic alcohols.catalysis communications,11(4),306-309. |
| MLA | Shi, Ruijuan,et al."MgO-supported Cu nanoparticles for efficient transfer dehydrogenation of primary aliphatic alcohols".catalysis communications 11.4(2009):306-309. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。