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Synthesis and surface properties of several nonionic-anionic surfactants with straight chain alkyl-benzyl hydrophobic group

文献类型:期刊论文

作者Wang, Xianguang; Yan, Feng; Li, Zhenquan; Zhang, Lu; Zhao, Sui; An, Jingyi; Yu, Jiayong
刊名Colloids and surfaces a-physicochemical and engineering aspects
出版日期2007-07-20
卷号302期号:1-3页码:532-539
关键词Nonionic-anionic surfactant Sodium straight chain alkyl-benzyl homogeneous polyoxyethylenated propane sulfonate Synthesis Krafft temperature Surface property
ISSN号0927-7757
DOI10.1016/j.colsurfa.2007.03.026
通讯作者Zhao, sui(zhaosui@mail.ipe.ac.cn)
英文摘要New nonionic-anionic surfactants of sodium straight chain alkyl benzyl alcohol homogeneous polyoxyethylenated propane sulfonates (abeps) were synthesized by the reaction of long chain alkyl (octyl, decyl and lauryl) benzyl chlorine with tri(ethylene glycol), followed by the reaction with 1,3-propane sultone. the physicochemical properties of abeps (e.g. krafft temperature and equilibrium surface tension) have been measured. abeps shows favorable solubility, and all of the krafft temperatures are below 0 degrees c. with increasing alkyl chain length, the critical micelle concentration (cmc), surface tension at cmc (gamma(cmc)) and surface area per molecule (a,,in) of abeps decrease, and the efficiency in reducing surface tension (pc20) and adsorption at the air/water interface relation to micellization (cmc/c-20) increase clearly. compared with fat alcohol ether sulfates with an analogous number of carbon atoms in hydrophobic group, the values of pc20 and cmc/c20 for abeps were more predominant. moreover, these surfactants in the article show the character of both nonionic and ionic surfactants due to its particular molecular structure. (c) 2007 elsevier b.v. all rights reserved.
WOS关键词SULFONATES ; SULFATES ; BEHAVIOR ; WATER
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000247192300078
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2383719
专题中国科学院大学
通讯作者Zhao, Sui
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Shengli Oilfield Co Ltd, Geol Res Inst, Dongying 257015, Peoples R China
推荐引用方式
GB/T 7714
Wang, Xianguang,Yan, Feng,Li, Zhenquan,et al. Synthesis and surface properties of several nonionic-anionic surfactants with straight chain alkyl-benzyl hydrophobic group[J]. Colloids and surfaces a-physicochemical and engineering aspects,2007,302(1-3):532-539.
APA Wang, Xianguang.,Yan, Feng.,Li, Zhenquan.,Zhang, Lu.,Zhao, Sui.,...&Yu, Jiayong.(2007).Synthesis and surface properties of several nonionic-anionic surfactants with straight chain alkyl-benzyl hydrophobic group.Colloids and surfaces a-physicochemical and engineering aspects,302(1-3),532-539.
MLA Wang, Xianguang,et al."Synthesis and surface properties of several nonionic-anionic surfactants with straight chain alkyl-benzyl hydrophobic group".Colloids and surfaces a-physicochemical and engineering aspects 302.1-3(2007):532-539.

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来源:中国科学院大学

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