A supramolecular chiroptical switch based on chitosan and anionic porphyrin complex film
文献类型：期刊论文
| 作者 | Liao, Bo1,2; Liu, Ruigang1; Huang, Yong1,3 |
| 刊名 | Polymer journal
 |
| 出版日期 | 2007 |
| 卷号 | 39期号:10页码:1071-1077 |
| 关键词 | Supramolecular chirality Chitosan Chiroptical switch Porphyrin |
| ISSN号 | 0032-3896 |
| DOI | 10.1295/polymj.pj2007036 |
| 通讯作者 | Huang, yong(yhuang@cashq.ac.cn) |
| 英文摘要 | A supramolecular chiroptical switch based on chitosan and tetrakis (4-sulfonatophenyl) porphine (tpps) complex films was prepared. the reversible changes of the chirality of the complex films were studied by uv-vis and circular dichroism (cd) spectra. it was found that the chirality of the complex films can be wiped off by being exposed to nh3 gas and subsequently recovered by being exposed to moist hcl gas. the complex film is stable and can stand at least 20 cycles of the switching to nh3 and hcl gases. there is no change in the above properties after the complex films were store in the air at room temperature. |
| WOS关键词 | CIRCULAR-DICHROISM ; AIR/WATER INTERFACE ; CATIONIC PORPHYRINS ; CHIRAL MEMORY ; ACHIRAL DYES ; TPPS ; MESO-TETRAKIS(4-SULFONATOPHENYL)PORPHINE ; AGGREGATION ; AMPHIPHILES ; DERIVATIVES |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000251595800011 |
| 出版者 | SOC POLYMER SCIENCE JAPAN |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2383900 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Huang, Yong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Joint Lab Polymer Sci & Mat,State Key Lab Polymer, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Chem, Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liao, Bo,Liu, Ruigang,Huang, Yong. A supramolecular chiroptical switch based on chitosan and anionic porphyrin complex film[J]. Polymer journal,2007,39(10):1071-1077. |
| APA | Liao, Bo,Liu, Ruigang,&Huang, Yong.(2007).A supramolecular chiroptical switch based on chitosan and anionic porphyrin complex film.Polymer journal,39(10),1071-1077. |
| MLA | Liao, Bo,et al."A supramolecular chiroptical switch based on chitosan and anionic porphyrin complex film".Polymer journal 39.10(2007):1071-1077. |
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来源：中国科学院大学
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