Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air
文献类型：期刊论文
| 作者 | Zhao, Miao1,2; Yu, Zhengkun1; Yan, Shenggang3; Li, Yang2 |
| 刊名 | tetrahedron letters
 |
| 出版日期 | 2009-08-12 |
| 卷号 | 50期号:32页码:4624-4628 |
| ISSN号 | 0040-4039 |
| 产权排序 | 2;1 |
| 通讯作者 | 余正坤 |
| 英文摘要 | transfer hydrogenation (th) of ketones and aldehydes was efficiently carried out in 2-propanol at room temperature by means of a ruthenium(ii) complex catalyst bearing a 2-(benzoimidazol-2-yl)-6-(pyrazol-1-yl)pyridine ligand. th of the ketone substrates proceeded in air, reaching final tofs of up to 59,400 h(-1), and the reduction of aldehydes proceeded under a nitrogen atmosphere to achieve final tofs of up to 5940 h(-1). (c) 2009 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric transfer-hydrogenation ; enantioselective transfer hydrogenation ; chemoselective transfer hydrogenation ; tethered ruthenium(ii) catalyst ; pyrazolyl-imidazolyl ligand ; aromatic ketones ; pnnp ligand ; complexes ; water ; bearing |
| 收录类别 | SCI ; CCR |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000267901800014 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102311]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Dalian Univ Technol, Coll Chem Engn, Dept Polymer Mat, Dalian 116012, Liaoning, Peoples R China 3.Dalian Maritime Univ, Electromech & Mat Engn Coll, Dalian 116026, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Miao,Yu, Zhengkun,Yan, Shenggang,et al. Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air[J]. tetrahedron letters,2009,50(32):4624-4628. |
| APA | Zhao, Miao,Yu, Zhengkun,Yan, Shenggang,&Li, Yang.(2009).Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air.tetrahedron letters,50(32),4624-4628. |
| MLA | Zhao, Miao,et al."Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air".tetrahedron letters 50.32(2009):4624-4628. |
入库方式： OAI收割
来源：大连化学物理研究所
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