Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts
文献类型:期刊论文
作者 | Fan, Yafang; Ma, Ding; Bao, Xinhe |
刊名 | catalysis letters
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出版日期 | 2009-07-01 |
卷号 | 130期号:3-4页码:286-290 |
关键词 | Methane activation Chloride methane Carbonylation Rhodium catalysts |
产权排序 | 1;1 |
通讯作者 | 包信和 |
英文摘要 | a new route for the indirect conversion of methane that makes use of the latest advance in methyl chloride production is reported. acetic acid was produced from the carbonylation of methyl chloride by carbon monoxide over a variety of catalysts. the presence of promoters was crucial for the carbonylation reaction. the yield of acetic acid reached 84.7% with rhcl(3) as catalyst and pph(3)/ki as promoters. the effects of reaction temperature, carbon monoxide pressure, and reaction time were investigated. the possible reaction mechanism was discussed. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | conversion ; hydrolysis ; activation ; chemistry ; iodide ; fuels |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000267330300003 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/102333] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Fan, Yafang,Ma, Ding,Bao, Xinhe. Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts[J]. catalysis letters,2009,130(3-4):286-290. |
APA | Fan, Yafang,Ma, Ding,&Bao, Xinhe.(2009).Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts.catalysis letters,130(3-4),286-290. |
MLA | Fan, Yafang,et al."Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts".catalysis letters 130.3-4(2009):286-290. |
入库方式: OAI收割
来源:大连化学物理研究所
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