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Chromium nitride films on stainless steel as bipolar plate for proton exchange membrane fuel cell

文献类型:期刊论文

作者Wu, Bo1; Fu, Yu2; Xu, Jun1; Lin, Guoqiang1; Hou, Ming3
刊名journal of power sources
出版日期2009-12-01
卷号194期号:2页码:976-980
关键词Chromium nitride Stainless steel bipolar plates Pulsed bias arc ion plating
产权排序3;5
通讯作者guoqiang lin
英文摘要a series of chromium nitride films are prepared on stainless steel substrates by pulsed bias arc ion plating (pbaip) at different n(2) flow rate as bipolar plates for proton exchange membrane fuel cell (pemfc). the film chemical composition and phase structure are characterized by x-ray photoelectron spectroscopy (xps) and x-ray diffractometry (xrd). the characterization results indicate that the nitrogen content of deposited films varies from 0.28 to 0.50, and the phase structure changes from mixtures of cr + cr(2)n, pure cr(2)n through cr(2)n+crn, to pure crn. the interfacial contact resistance between samples and carbon paper is measured by wang's method, and a minimum value of 5.8 m omega cm(2) is obtained under 1.2 mpa compaction force. the anticorrosion property is examined by potentiodynamic test in the simulated corrosive circumstance of the pemfc under 25 degrees c, and the lowest corrosive current density of 5.9 x 10(-7) a cm(-2) is obtained at 0.6v (vs. sce). stainless steel substrates coated by the film with lowest contact resistance are chosen as the bipolar plates to assemble cells. an average voltage value of 0.62v is achieved at 500 ma cm(-2), which is close to that of the cell with ag-plated bipolar plates. crown copyright (c) 2009 published by elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]electrochemistry ; energy & fuels
研究领域[WOS]electrochemistry ; energy & fuels
关键词[WOS]cr-nitrides ; ni-50cr ; alloys ; growth ; cost
收录类别SCI
原文出处false
语种英语
WOS记录号WOS:000270620500052
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/102365]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116085, Peoples R China
2.Sunrise Power Co Ltd, Dalian 116025, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell R&D Ctr, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wu, Bo,Fu, Yu,Xu, Jun,et al. Chromium nitride films on stainless steel as bipolar plate for proton exchange membrane fuel cell[J]. journal of power sources,2009,194(2):976-980.
APA Wu, Bo,Fu, Yu,Xu, Jun,Lin, Guoqiang,&Hou, Ming.(2009).Chromium nitride films on stainless steel as bipolar plate for proton exchange membrane fuel cell.journal of power sources,194(2),976-980.
MLA Wu, Bo,et al."Chromium nitride films on stainless steel as bipolar plate for proton exchange membrane fuel cell".journal of power sources 194.2(2009):976-980.

入库方式: OAI收割

来源:大连化学物理研究所

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