Catalytic conversion of cellulose into ethylene glycol over supported carbide catalysts
文献类型：期刊论文
| 作者 | Ji, Na1,2; Zhang, Tao1; Zheng, Mingyuan1; Wang, Aiqin1; Wang, Hui1,2; Wang, Xiaodong1; Shu, Yuying1; Stottlemyer, Alan L.3; Chen, Jingguang G.3 |
| 刊名 | catalysis today
 |
| 出版日期 | 2009-09-30 |
| 卷号 | 147期号:2页码:77-85 |
| 关键词 | Biofuels Catalysis Cellulose Sustainable chemistry Tungsten carbides |
| 产权排序 | 1;1 |
| 通讯作者 | 张涛 ; 陈经广 |
| 英文摘要 | in the current paper we present a combined catalytic and surface science studies to evaluate the utilization of carbide catalysts for the conversion of cellulose to polyols, especially to ethylene glycol (eg). based on catalytic studies over a w(2)c catalyst, the eg yield has been optimized by varying h(2) pressure, reaction temperature and time. the catalytic performance has been compared for several types of supported catalysts, including tungsten carbides, molybdenum carbides and platinum on different supports. among all the catalysts, tungsten carbide supported on activated carbon, w(2)c/ac, shows the highest eg yield, which is further enhanced to 61% with the promotion of ni. the corresponding surface science studies indicate that the enhanced eg yield is at least partially due to a weaker bonding between eg and ni-promoted tungsten carbide surface. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | transition-metal carbides ; hydrazine decomposition ; tungsten carbide ; surface science ; hydrolysis ; carbon ; molybdenum ; methanol ; water ; electrocatalysts |
| 收录类别 | SCI ; ISTP |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000269765200004 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102401]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Univ Delaware, Dept Chem Engn, CCST, Newark, DE 19716 USA |
| 推荐引用方式 GB/T 7714 | Ji, Na,Zhang, Tao,Zheng, Mingyuan,et al. Catalytic conversion of cellulose into ethylene glycol over supported carbide catalysts[J]. catalysis today,2009,147(2):77-85. |
| APA | Ji, Na.,Zhang, Tao.,Zheng, Mingyuan.,Wang, Aiqin.,Wang, Hui.,...&Chen, Jingguang G..(2009).Catalytic conversion of cellulose into ethylene glycol over supported carbide catalysts.catalysis today,147(2),77-85. |
| MLA | Ji, Na,et al."Catalytic conversion of cellulose into ethylene glycol over supported carbide catalysts".catalysis today 147.2(2009):77-85. |
入库方式： OAI收割
来源：大连化学物理研究所
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