Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation
文献类型：期刊论文
| 作者 | Zhu, Mingyuan1,2; Sun, Gongquan1; Xin, Qin1,3 |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2009-02-01 |
| 卷号 | 54期号:5页码:1511-1518 |
| 关键词 | Direct ethanol fuel cell PtSn catalyst Alloying degree Ethanol electro-oxidation Anode catalyst |
| 产权排序 | 1;1 |
| 通讯作者 | 孙公权 |
| 英文摘要 | carbon-supported binary ptsn catalysts with varied alloying degree were synthesized in different processes and denoted as ptsn/c-b, ptsn/c-eg and ptsno(2)/c, respectively. x-ray diffraction (xrd) characterizations showed that ptsn/c-b catalyst displayed the highest alloying degree, while ptsno(2)/c catalyst had the lowest one among these samples. x-ray photoelectron spectroscopy (xps) results revealed that the non-alloyed sn existed in an oxidized state on the surfaces of these catalysts. by evaluating the electrocatalytic activity and analyzing the final products of ethanol oxidation reaction (eor) on these catalysts, it was found that ptsno(2)/c catalyst enhanced the products yield of acetic acid products and ptsn/c-b catalyst promoted the entire activity for eor. it was proposed that non-alloyed sno(2) species enhanced the bi-functional mechanism, whereas ptsn alloy phase strengthened the electronic effect of ptsn/c catalyst. (c) 2008 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | fuel-cells ; structural characteristics ; sn electrocatalysts ; methanol oxidation ; ternary catalysts ; formic-acid ; part ii ; platinum ; reduction ; performance |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000263006100018 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102423]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dirrect Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Mingyuan,Sun, Gongquan,Xin, Qin. Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation[J]. electrochimica acta,2009,54(5):1511-1518. |
| APA | Zhu, Mingyuan,Sun, Gongquan,&Xin, Qin.(2009).Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation.electrochimica acta,54(5),1511-1518. |
| MLA | Zhu, Mingyuan,et al."Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation".electrochimica acta 54.5(2009):1511-1518. |
入库方式： OAI收割
来源：大连化学物理研究所
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