Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene
文献类型：期刊论文
| 作者 | Zhao, Yujun1,2; Zhou, Jin2; Zhang, Jianguo2; Wang, Shudong2 |
| 刊名 | catalysis letters
 |
| 出版日期 | 2009-09-01 |
| 卷号 | 131期号:3-4页码:597-605 |
| 关键词 | Ruthenium Benzene Cyclohexene Hydrogenation Cordierite monolith |
| 产权排序 | 2;1 |
| 通讯作者 | 王树东 |
| 英文摘要 | a series of ru/al2o3/cordierite monolithic catalysts were prepared and characterized by bet, xrd, tpr, tem and sem-edax. the catalytic performances in selective hydrogenation of benzene to cyclohexene were investigated in a continuous fixed-bed reactor. the preparation conditions significantly influence morphology, particle size, and surface area of the catalyst, subsequently affecting the catalytic performances. it was found that higher calcination temperature of the ru-based monolithic catalyst led to the conglomeration and crystallite growth of the t-ruo2, which will decrease the catalytic activity. the lower thickness and the larger pore size of the alumina washcoating layer are the preferential choices to obtain higher cyclohexene selectivity due to the improved internal mass transfer of cyclohexene. it was also found that high ruthenium loading resulted in deep hydrogenation of cyclohexene. moreover, the reduction temperature was optimized to 473 k and excess high temperature led to the deterioration of both activity and cyclohexene selectivity. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | liquid-phase hydrogenation ; efficient 3-phase reactors ; aqueous salt solution ; ruthenium catalysts ; performance |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000269883300040 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102453]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Tianjin Univ, Key Lab Green Chem Technol, Sch Chem Engn & Technol, Minist Educ, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Modern Chem Lab, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yujun,Zhou, Jin,Zhang, Jianguo,et al. Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene[J]. catalysis letters,2009,131(3-4):597-605. |
| APA | Zhao, Yujun,Zhou, Jin,Zhang, Jianguo,&Wang, Shudong.(2009).Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene.catalysis letters,131(3-4),597-605. |
| MLA | Zhao, Yujun,et al."Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene".catalysis letters 131.3-4(2009):597-605. |
入库方式： OAI收割
来源：大连化学物理研究所
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