Template-Synthesized Porous Silicon Carbide as an Effective Host for Zeolite Catalysts
文献类型:期刊论文
作者 | Gu, Lijun; Ma, Ding; Yao, Songdong; Liu, Xiumei; Han, Xiuwen; Shen, Wenjie; Bao, Xinhe |
刊名 | chemistry-a european journal
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出版日期 | 2009 |
卷号 | 15期号:48页码:13449-13455 |
关键词 | dehydroaromatization heterogeneous catalysis silicon carbide template synthesis zeolites |
产权排序 | 1;1 |
通讯作者 | 马丁 ; 包信和 |
英文摘要 | a facile method has been developed for the fabrication of porous silicon carbide (sic) by means of sintering a mixture of sic powder and carbon pellets at a relatively lower temperature, that is, 1450 degrees c, in air. the pore density and the total pore volume of the resulting porous sic could be tuned by changing the initial sic/c weight ratio. the structure evolution and the associated property changes during the preparation were examined through x-ray diffraction, scanning electron microscopy, thermogravimetric analysis, (29)si magic-angle spinning (mas) nmr spectroscopy, and mercury-intrusion porosimetry analyses. silica and sio(x)c(y) ceramics formed in situ during the calcination process acted as binders of the porous sic grains. the porous sic can be used as a host for the growth of zsm-5 zeolite crystals to form the zsm-5/porous-sic composite material. after loading another catalytic active component of molybdenum, a novel catalytic material, mo-zsm-5/porous-sic, was obtained, which exhibited improved catalytic activity in the methane dehydroaromatization reaction. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | mo-95 nmr-spectroscopy ; methane aromatization ; ceramics ; foams ; dehydroaromatization ; coatings ; polymer ; transformation ; fabrication ; crystals |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000273856400024 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/102483] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Gu, Lijun,Ma, Ding,Yao, Songdong,et al. Template-Synthesized Porous Silicon Carbide as an Effective Host for Zeolite Catalysts[J]. chemistry-a european journal,2009,15(48):13449-13455. |
APA | Gu, Lijun.,Ma, Ding.,Yao, Songdong.,Liu, Xiumei.,Han, Xiuwen.,...&Bao, Xinhe.(2009).Template-Synthesized Porous Silicon Carbide as an Effective Host for Zeolite Catalysts.chemistry-a european journal,15(48),13449-13455. |
MLA | Gu, Lijun,et al."Template-Synthesized Porous Silicon Carbide as an Effective Host for Zeolite Catalysts".chemistry-a european journal 15.48(2009):13449-13455. |
入库方式: OAI收割
来源:大连化学物理研究所
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