Trace Water-Promoted Oxidation of Benzylic Alcohols with Molecular Oxygen Catalyzed by Vanadyl Sulfate and Sodium Nitrite under Mild Conditions
文献类型：期刊论文
| 作者 | Du, Zhongtian1,2; Miao, Hong1; Ma, Hong1; Sun, Zhiqiang1; Ma, Jiping1,2; Xu, Jie1 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2009-03-01 |
| 卷号 | 351期号:4页码:558-562 |
| 关键词 | benzylic alcohols molecular oxygen nitrite oxidation vanadium |
| 产权排序 | 1;1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | an inexpensive catalytic system consisting of vanadyl sulfate and sodium nitrite was developed for the oxidation of benzylic alcohols with molecular oxygen under mild conditions. benzyl alcohols with various substitutions were efficiently converted to their corresponding aldehydes with high conversion and selectivity under 80 c (e.g., 4-nitrobenzyl alcohol was smoothly oxidized to 4-nitrobenzyl aldehyde with 94% yield under 0.5 mpa of molecular oxygen). halogen, noble metals, extra base or complicated ligands were avoided. addition of a trace of water to this system before the reaction was crucial for the high efficiency. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | selective aerobic oxidation ; transition-metal-free ; efficient heterogeneous catalyst ; stabilized gold nanoclusters ; carbonyl-compounds ; solvent-free ; propargylic alcohols ; ruthenium catalyst ; hydrogen-peroxide ; oxidase catalysis |
| 收录类别 | SCI ; CCR |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000264831500009 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102491]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Zhongtian,Miao, Hong,Ma, Hong,et al. Trace Water-Promoted Oxidation of Benzylic Alcohols with Molecular Oxygen Catalyzed by Vanadyl Sulfate and Sodium Nitrite under Mild Conditions[J]. advanced synthesis & catalysis,2009,351(4):558-562. |
| APA | Du, Zhongtian,Miao, Hong,Ma, Hong,Sun, Zhiqiang,Ma, Jiping,&Xu, Jie.(2009).Trace Water-Promoted Oxidation of Benzylic Alcohols with Molecular Oxygen Catalyzed by Vanadyl Sulfate and Sodium Nitrite under Mild Conditions.advanced synthesis & catalysis,351(4),558-562. |
| MLA | Du, Zhongtian,et al."Trace Water-Promoted Oxidation of Benzylic Alcohols with Molecular Oxygen Catalyzed by Vanadyl Sulfate and Sodium Nitrite under Mild Conditions".advanced synthesis & catalysis 351.4(2009):558-562. |
入库方式： OAI收割
来源：大连化学物理研究所
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