The Pd-catalyzed hydrodechlorination of chlorophenols in aqueous solutions under mild conditions: A promising approach to practical use in wastewater
文献类型：期刊论文
| 作者 | Xia, Chuanhai1; Liu, Ying1; Zhou, Shiwei1; Yang, Cuiyun1; Liu, Sujing1; Xu, Jie2; Yu, Junbao1; Chen, Jiping2; Liang, Xinmiao2 |
| 刊名 | journal of hazardous materials
 |
| 出版日期 | 2009-09-30 |
| 卷号 | 169期号:1-3页码:1029-1033 |
| 关键词 | Catalytic hydrodechlorination Pd/C Chlorophenols Aqueous solutions Solvent effect |
| 产权排序 | 2;6 |
| 通讯作者 | chuanhai xia |
| 英文摘要 | catalytic hydrotreating of chlorophenols was carried out in water with pd/c at 25 degrees c under atmospheric pressure. 1.0% (w/w) monocholophenols was completely dechlorinated within 60 min. phenol, cyclohexanone and cyclohexanol were formed. in contrast to the dechlorination of monochlorophenols, the hydrogenation reaction of polychlorinated phenols became difficult and reaction rates were strongly dependent upon the number of the chlorine atoms. the solvent property had a considerably important influence on the dechlorination reaction. water as a solvent showed more advantages than organic solvents. it was much easier to be hydrodechlorinated for chlorophenols in aqueous solutions. however, the presence of thf, dioxane, dmso or dmf in water was disadvantageous to the reaction and easily to cause pd/c deactivation. additionally, when different halogenated organic compounds were present in aqueous solution, the dehalogenation reaction was the competitive hydrogenation process. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; life sciences & biomedicine |
| 类目[WOS] | engineering, environmental ; engineering, civil ; environmental sciences |
| 研究领域[WOS] | engineering ; environmental sciences & ecology |
| 关键词[WOS] | liquid-phase hydrodechlorination ; raney-nickel catalyst ; palladium catalysts ; fly-ash ; dechlorination ; hydrogenation ; hydrodehalogenation ; solvent ; destruction ; kinetics |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000268967200142 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/102503]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.CAS, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China 2.CAS, Dalian Inst Chem Phys, Dalian 116021, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Chuanhai,Liu, Ying,Zhou, Shiwei,et al. The Pd-catalyzed hydrodechlorination of chlorophenols in aqueous solutions under mild conditions: A promising approach to practical use in wastewater[J]. journal of hazardous materials,2009,169(1-3):1029-1033. |
| APA | Xia, Chuanhai.,Liu, Ying.,Zhou, Shiwei.,Yang, Cuiyun.,Liu, Sujing.,...&Liang, Xinmiao.(2009).The Pd-catalyzed hydrodechlorination of chlorophenols in aqueous solutions under mild conditions: A promising approach to practical use in wastewater.journal of hazardous materials,169(1-3),1029-1033. |
| MLA | Xia, Chuanhai,et al."The Pd-catalyzed hydrodechlorination of chlorophenols in aqueous solutions under mild conditions: A promising approach to practical use in wastewater".journal of hazardous materials 169.1-3(2009):1029-1033. |
入库方式： OAI收割
来源：大连化学物理研究所
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