Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}]
文献类型：期刊论文
| 作者 | Yang, Jing-Mu1,2; Hu, Bin1; Ge, Jin1,2; Xia, Chun-Gu1 |
| 刊名 | Journal of chemical research-s
 |
| 出版日期 | 2008-06-01 |
| 期号 | 6页码:322-323 |
| 关键词 | Homometallic chiral cluster Enantioseparation Acetylferrocenyl-thiosemicarbazone X-ray structure |
| ISSN号 | 0308-2342 |
| DOI | 10.3184/030823408x327884 |
| 通讯作者 | Xia, chun-gu(cgxia@lzb.ac.cn) |
| 英文摘要 | Reaction of ru-3(co)(12) with the thio-schiff base ligand acetylferrocenyl-thiosemicarbazone provides a one-step synthesis of the chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}] as a racemic mixture. one molecule of thiosemicarbazone was consumed in the cluster formation process, in which the ligand was deprotonated and acted as a bidentate n, s donor as well as bridging. the title cluster has been characterised by nmr, ir, hplc and an x-ray structure determination. |
| WOS关键词 | COORDINATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000259553600007 |
| 出版者 | SCIENCE REVIEWS LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2385057 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xia, Chun-Gu |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Jing-Mu,Hu, Bin,Ge, Jin,et al. Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}][J]. Journal of chemical research-s,2008(6):322-323. |
| APA | Yang, Jing-Mu,Hu, Bin,Ge, Jin,&Xia, Chun-Gu.(2008).Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}].Journal of chemical research-s(6),322-323. |
| MLA | Yang, Jing-Mu,et al."Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}]".Journal of chemical research-s .6(2008):322-323. |
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来源：中国科学院大学
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