中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and properties of aromatic side chained n-acyltaurate surfactants

文献类型:期刊论文

作者Yan, Feng1,2; Wang, Xian-Guang1,2; Li, Zhen-Quan3; Zhang, Lu1; Zhao, Sui1; Yu, Jia-Yong1
刊名Journal of dispersion science and technology
出版日期2008-03-01
卷号29期号:3页码:387-396
关键词Sodium n-2-(4-alkylaryloxy)-tetradecariolytaurinate Critical micelle concentration Fluorescence spectra Surfactant
ISSN号0193-2691
DOI10.1080/01932690701718628
通讯作者Zhao, sui(zhaosui@mail.ipc.ac.cn)
英文摘要A series of anionic n-acyltaurate surfactants, side chain containing aromatic nucleus (abbreviated as saatt), were synthesized via williamson reaction, hydrolyzation, and acylation. krafft temperatures and surface properties of these surfactants at 30 degrees c, that is, critical micelle concentration, cmc, surface excess concentration, gamma(max), surface area demand per molecule, a(min), efficiency in surface tension reduction, pc(20), effectiveness in surface tension reduction, pi(cmc) and cmc/c-20 parameter were determined. it was shown that these surfactants exhibit good solubility which was confirmed by measuring krafft temperature. the cmc of saatt was much smaller than that of conventional surfactants with similar effective carbon numbers, and shifted to lower concentration with increasing hydrocarbon chain length. in addition, the gamma(cmc) decreased with decrease in gamma max. the pc(20) and the cmc/c-20 got larger with the increase in hydrocarbon chain length. from the fluorescence intensity ratios of i-1 (373 nm) and i-3 (384 nm) using pyrene as a probe, it was indicated that the molecules of saatt formed loose micelles with a broad size distribution.
WOS关键词SELF-ASSOCIATION ; HETEROGEMINI SURFACTANTS ; SODIUM TAUROCHOLATE ; GEMINI SURFACTANTS ; IONIC SURFACTANTS ; AQUEOUS-SOLUTION ; TAURODEOXYCHOLATE ; SOLUBILIZATION ; MICELLIZATION ; MICELLES
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000253944200012
出版者TAYLOR & FRANCIS INC
URI标识http://www.irgrid.ac.cn/handle/1471x/2385072
专题中国科学院大学
通讯作者Zhao, Sui
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
3.Geol Res Inst Shengli Oilfield Co Ltd, SINOPEC, Dongying, Peoples R China
推荐引用方式
GB/T 7714
Yan, Feng,Wang, Xian-Guang,Li, Zhen-Quan,et al. Synthesis and properties of aromatic side chained n-acyltaurate surfactants[J]. Journal of dispersion science and technology,2008,29(3):387-396.
APA Yan, Feng,Wang, Xian-Guang,Li, Zhen-Quan,Zhang, Lu,Zhao, Sui,&Yu, Jia-Yong.(2008).Synthesis and properties of aromatic side chained n-acyltaurate surfactants.Journal of dispersion science and technology,29(3),387-396.
MLA Yan, Feng,et al."Synthesis and properties of aromatic side chained n-acyltaurate surfactants".Journal of dispersion science and technology 29.3(2008):387-396.

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来源:中国科学院大学

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