Unprecedented 2-d hydrated proton encapsulated in supramolecular framework built of [mo3o4(c2o4)(h2o)(3)](2-)
文献类型:期刊论文
作者 | Zhao, Jun1,2; Xu, Li1 |
刊名 | Inorganic chemistry communications
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出版日期 | 2008-04-01 |
卷号 | 11期号:4页码:353-357 |
关键词 | Hydrated proton Water sheet H-bonds |
ISSN号 | 1387-7003 |
DOI | 10.1016/j.inoche.2007.12.013 |
通讯作者 | Xu, li(xli@fjirsm.ac.cn) |
英文摘要 | The unprecedented 2-d hydrated proton consisting of the fused h+(h2o)(18) ring has been found in et4n h+(h2o)(8) center dot [mo3o4(c2o4)(3)(h2o)(3)] (1). the proton has been found to be located around the disordered three-connected nodes of the water sheet as revealed by the unusually short o center dot center dot center dot h+center dot center dot center dot o bonds. the protonated water layer is supported by the h-bonds between the ring water molecules and the host framework constructed from the triangular trimolybdenum(iv) cluster dianion, [mo3o4(c2o4)(3)(h2o)(3)](2-). (c) 2008 elsevier b.v. all rights reserved. |
WOS关键词 | WATER CLUSTERS ; NEUTRON-DIFFRACTION ; X-RAY ; COMPLEX ; ION ; MOLYBDENUM(IV) ; MORPHOLOGY ; MOLECULES ; MECHANISM ; DYNAMICS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
WOS记录号 | WOS:000255466600001 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2385095 |
专题 | 中国科学院大学 |
通讯作者 | Xu, Li |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Jun,Xu, Li. Unprecedented 2-d hydrated proton encapsulated in supramolecular framework built of [mo3o4(c2o4)(h2o)(3)](2-)[J]. Inorganic chemistry communications,2008,11(4):353-357. |
APA | Zhao, Jun,&Xu, Li.(2008).Unprecedented 2-d hydrated proton encapsulated in supramolecular framework built of [mo3o4(c2o4)(h2o)(3)](2-).Inorganic chemistry communications,11(4),353-357. |
MLA | Zhao, Jun,et al."Unprecedented 2-d hydrated proton encapsulated in supramolecular framework built of [mo3o4(c2o4)(h2o)(3)](2-)".Inorganic chemistry communications 11.4(2008):353-357. |
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来源:中国科学院大学
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