Electrochemical durability of gas diffusion layer under simulated proton exchange membrane fuel cell conditions
文献类型:期刊论文
作者 | Chen, Guobao1,2; Zhang, Huamin1; Ma, Haipeng1; Zhong, Hexiang1 |
刊名 | international journal of hydrogen energy |
出版日期 | 2009-10-01 |
卷号 | 34期号:19页码:8185-8192 |
关键词 | Gas diffusion layer Polymer electrolyte membrane fuel cell Electrochemical durability Carbon corrosion |
通讯作者 | 张华民 |
产权排序 | 1;1 |
英文摘要 | an effective ex-situ method for characterizing electrochemical durability of a gas diffusion layer (gdl) under simulated polymer electrolyte membrane fuel cell (pemfc) conditions is reported in this article. electrochemical oxidation of the gdls are studied following potentiostatic treatments up to 96 h holding at potentials from 1.0 to 1.4 v (vs.sce) in 0.5 mol l(-1) h(2)so(4). from the analysis of morphology, resistance, gas permeability and contact angle, the characteristics of the fresh gdl and the oxidized gdls are compared. it is found that the maximum power densities of the fuel cells with the oxidized gdls hold at 1.2 and 1.4 v (vs.sce) for 96 h decreased 178 and 486 mw cm(-2), respectively. the electrochemical impedance spectra measured at 1500 ma cm(-2) are also presented and they reveal that the ohmic resistance, charge-transfer and mass-transfer resistances of the fuel cell changed significantly due to corrosion at high potential. (c) 2009 professor t. nejat veziroglu. published by elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
关键词[WOS] | composite carbon-black ; micro-porous layer ; catalyst layer ; performance ; cathode ; pemfc ; electrodes ; corrosion |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000271354700037 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/102645] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.CAS, Dalian Inst Chem Phys, Key Mat Lab PEMFCs, Dalian 116023, Peoples R China 2.CAS, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Guobao,Zhang, Huamin,Ma, Haipeng,et al. Electrochemical durability of gas diffusion layer under simulated proton exchange membrane fuel cell conditions[J]. international journal of hydrogen energy,2009,34(19):8185-8192. |
APA | Chen, Guobao,Zhang, Huamin,Ma, Haipeng,&Zhong, Hexiang.(2009).Electrochemical durability of gas diffusion layer under simulated proton exchange membrane fuel cell conditions.international journal of hydrogen energy,34(19),8185-8192. |
MLA | Chen, Guobao,et al."Electrochemical durability of gas diffusion layer under simulated proton exchange membrane fuel cell conditions".international journal of hydrogen energy 34.19(2009):8185-8192. |
入库方式: OAI收割
来源:大连化学物理研究所
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