Investigation on the interactions between polyurethane and metal chloride
文献类型：期刊论文
| 作者 | Liu, Xinhai1,3; Zhao, Ying1; Liu, Zhi2; Wang, Dujin1; Wu, Jinguang2; Xu, Duanfu1 |
| 刊名 | Journal of molecular structure
 |
| 出版日期 | 2008-12-15 |
| 卷号 | 892期号:1-3页码:200-204 |
| 关键词 | Polyurethane Metal ion Interaction Phase separation |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2008.05.025 |
| 通讯作者 | Zhao, ying(yzhao@iccas.ac.cn) |
| 英文摘要 | The aim of this article is to investigate the effect of interactions between metal ions and polyurethanes(pu) on the properties of polyurethanes. in this report, interaction between metal ions(y(3+), la(3+), ca(2+), cu(2+), and li(+)) and polyurethanes was investigated by ft-ir spectroscopy, theological method and tem technique. compared with the pure pu, obvious variation of carbonyl group vibration can be observed from the ir spectra of pu-ycl(3), pu-cucl(2) and pu-licl composites, which indicated that there were interactions between these metal ions and the polar carbonyl groups of pu. although the ir spectra of pu-cacl(2) systems showed little changes, the difference of theological behavior between pu-cacl(2)-dmf solution system and pure pili solution implied that the aggregation state of pu changed in the presence of ca(2+) ions, which provided the evidence that interactions between metal ions and the molecular chains of pu occurred in the solution, and similar behavior can be observed in pu-ycl(3), pu-cucl(2) and pu-licl solution systems, respectively. tem of pu-lacl(3) results revealed that pu possesses the ability to coordinate with metal ions, resulting in the formation of the ion clusters and phase separation in the pu-metal ion systems. in summary, there are interactions between metal ions and the carbonyl groups of pu in solid state and in dmf solution, which may provide a new way to modify the properties of polyurethanes. (c) 2008 elsevier b.v. all rights reserved. |
| WOS关键词 | INFRARED TEMPERATURE ; POLYAMIDE ; POLYMERS ; SYSTEM ; FTIR ; IONS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000261711400033 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2386378 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhao, Ying |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem,Beijing Natl La, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xinhai,Zhao, Ying,Liu, Zhi,et al. Investigation on the interactions between polyurethane and metal chloride[J]. Journal of molecular structure,2008,892(1-3):200-204. |
| APA | Liu, Xinhai,Zhao, Ying,Liu, Zhi,Wang, Dujin,Wu, Jinguang,&Xu, Duanfu.(2008).Investigation on the interactions between polyurethane and metal chloride.Journal of molecular structure,892(1-3),200-204. |
| MLA | Liu, Xinhai,et al."Investigation on the interactions between polyurethane and metal chloride".Journal of molecular structure 892.1-3(2008):200-204. |
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来源：中国科学院大学
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