Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts
文献类型:期刊论文
作者 | Wen, Zhenhai1,2; Wang, Qiang1; Li, Jinghong1 |
刊名 | Advanced functional materials
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出版日期 | 2008-03-25 |
卷号 | 18期号:6页码:959-964 |
ISSN号 | 1616-301X |
DOI | 10.1002/adfm.200700707 |
通讯作者 | Wen, zhenhai() |
英文摘要 | A facile method is developed to synthesize aligned arrays of open-ended carbon nanotubes (cnts) via in situ glucose polymerization in the inner pores of anodic aluminum oxide templates under hydrothermal conditions, followed by carbonization at high temperature. pt nanoparticles are decorated on the surfaces of the as-prepared cnts using the incipient wet method based on the use of nabh4 as a reductant. characterization of the resulting structures by transmission electron microscopy and field-emission scanning electron microscopy demonstrates that the pt nanoparticles are anchored on both the inner and outer walls of cnts, thus giving rise to a shell-core-shell-like nanotube composite. the electrocatalytic properties of the pt-cnt-pt electrodes are investigated for methanol oxidation by cyclic voltammetry and chronoamperometric measurements. it is found that the hybrid electrodes show superior catalytic performance compared to commercial carbon-black-supported pt. the increased catalytic efficiency of pt might be a result of the unique morphology of these structures. |
WOS关键词 | ALUMINUM-OXIDE FILM ; METAL NANOPARTICLES ; SUPERCRITICAL-FLUID ; METHANOL OXIDATION ; IN-SITU ; MEMBRANES ; SINGLE ; GROWTH ; MICROTUBULES ; NANOCHANNELS |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
语种 | 英语 |
WOS记录号 | WOS:000254872100015 |
出版者 | WILEY-V C H VERLAG GMBH |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2386496 |
专题 | 中国科学院大学 |
通讯作者 | Wen, Zhenhai |
作者单位 | 1.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Wen, Zhenhai,Wang, Qiang,Li, Jinghong. Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts[J]. Advanced functional materials,2008,18(6):959-964. |
APA | Wen, Zhenhai,Wang, Qiang,&Li, Jinghong.(2008).Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts.Advanced functional materials,18(6),959-964. |
MLA | Wen, Zhenhai,et al."Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts".Advanced functional materials 18.6(2008):959-964. |
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来源:中国科学院大学
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