中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts

文献类型:期刊论文

作者Wen, Zhenhai1,2; Wang, Qiang1; Li, Jinghong1
刊名Advanced functional materials
出版日期2008-03-25
卷号18期号:6页码:959-964
ISSN号1616-301X
DOI10.1002/adfm.200700707
通讯作者Wen, zhenhai()
英文摘要A facile method is developed to synthesize aligned arrays of open-ended carbon nanotubes (cnts) via in situ glucose polymerization in the inner pores of anodic aluminum oxide templates under hydrothermal conditions, followed by carbonization at high temperature. pt nanoparticles are decorated on the surfaces of the as-prepared cnts using the incipient wet method based on the use of nabh4 as a reductant. characterization of the resulting structures by transmission electron microscopy and field-emission scanning electron microscopy demonstrates that the pt nanoparticles are anchored on both the inner and outer walls of cnts, thus giving rise to a shell-core-shell-like nanotube composite. the electrocatalytic properties of the pt-cnt-pt electrodes are investigated for methanol oxidation by cyclic voltammetry and chronoamperometric measurements. it is found that the hybrid electrodes show superior catalytic performance compared to commercial carbon-black-supported pt. the increased catalytic efficiency of pt might be a result of the unique morphology of these structures.
WOS关键词ALUMINUM-OXIDE FILM ; METAL NANOPARTICLES ; SUPERCRITICAL-FLUID ; METHANOL OXIDATION ; IN-SITU ; MEMBRANES ; SINGLE ; GROWTH ; MICROTUBULES ; NANOCHANNELS
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
语种英语
WOS记录号WOS:000254872100015
出版者WILEY-V C H VERLAG GMBH
URI标识http://www.irgrid.ac.cn/handle/1471x/2386496
专题中国科学院大学
通讯作者Wen, Zhenhai
作者单位1.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wen, Zhenhai,Wang, Qiang,Li, Jinghong. Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts[J]. Advanced functional materials,2008,18(6):959-964.
APA Wen, Zhenhai,Wang, Qiang,&Li, Jinghong.(2008).Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts.Advanced functional materials,18(6),959-964.
MLA Wen, Zhenhai,et al."Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts".Advanced functional materials 18.6(2008):959-964.

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来源:中国科学院大学

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