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Solvothermal synthesis of well-dispersed mf(2) (m = ca, sr, ba) nanocrystals and their optical properties

文献类型:期刊论文

作者Zhang, Xiaoming1,2; Quan, Zewei1,2; Yang, Jun1,2; Yang, Piaoping1; Lian, Hongzhou1; Lin, Jun1
刊名Nanotechnology
出版日期2008-02-20
卷号19期号:7页码:8
ISSN号0957-4484
DOI10.1088/0957-4484/19/7/075603
通讯作者Lin, jun(jlin@ciac.jl.cn)
英文摘要Mf(2) (m = ca, sr, ba) nanocrystals (ncs) were synthesized via a solvothermal process in the presence of oleic acid and characterized by x-ray diffraction (xrd), transmission electron microscopy (tem), fourier transform infrared (ft-ir) spectra, uv/vis absorption spectra, photoluminescence (pl) excitation and emission spectra, and lifetimes, respectively. in the synthetic process, oleic acid as a surfactant played a crucial role in confining the growth and solubility of the mf(2) ncs. the as-prepared caf(2), srf(2) and baf(2) ncs present morphologies of truncated octahedron, cube and sheet in a narrow distribution, respectively. possible growth mechanisms were proposed to explain these results. the as-prepared ncs are highly crystalline and can be well dispersed in cyclohexane to form stable and clear colloidal solutions, which demonstrate strong emission bands centred at 400 nm in photoluminescence (pl) spectra compared with the cyclohexane solvent. the pl properties of the colloidal solutions of the as-prepared ncs can be ascribed to the trap states of surface defects.
WOS关键词ONE-DIMENSIONAL NANOSTRUCTURES ; EARTH FLUORIDE NANOCRYSTALS ; HYDROTHERMAL SYNTHESIS ; SINGLE-CRYSTALS ; SEMICONDUCTOR NANOCRYSTALS ; HIGHLY CRYSTALLINE ; SHAPE CONTROL ; QUANTUM-DOT ; IRON-OXIDE ; NANOPARTICLES
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
语种英语
WOS记录号WOS:000252967300015
出版者IOP PUBLISHING LTD
URI标识http://www.irgrid.ac.cn/handle/1471x/2386603
专题中国科学院大学
通讯作者Lin, Jun
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Applicat Rare Earth Resources, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xiaoming,Quan, Zewei,Yang, Jun,et al. Solvothermal synthesis of well-dispersed mf(2) (m = ca, sr, ba) nanocrystals and their optical properties[J]. Nanotechnology,2008,19(7):8.
APA Zhang, Xiaoming,Quan, Zewei,Yang, Jun,Yang, Piaoping,Lian, Hongzhou,&Lin, Jun.(2008).Solvothermal synthesis of well-dispersed mf(2) (m = ca, sr, ba) nanocrystals and their optical properties.Nanotechnology,19(7),8.
MLA Zhang, Xiaoming,et al."Solvothermal synthesis of well-dispersed mf(2) (m = ca, sr, ba) nanocrystals and their optical properties".Nanotechnology 19.7(2008):8.

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来源:中国科学院大学

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