Synthesis and surface characterization of an amphiphilic fluorinated copolymer via emulsifier-free emulsion polymerization of raft
文献类型：期刊论文
| 作者 | Xu, Shouping1,2; Liu, Weiqu1 |
| 刊名 | Journal of fluorine chemistry
 |
| 出版日期 | 2008-02-01 |
| 卷号 | 129期号:2页码:125-130 |
| 关键词 | Amphiphilic copolymer Fluorinated Raft Emulsifier-free |
| ISSN号 | 0022-1139 |
| DOI | 10.1016/j.jfluchem.2007.09.008 |
| 通讯作者 | Liu, weiqu(liuwq@gic.ac.cn) |
| 英文摘要 | The hydrophobic monomer dodecafluoroheptyl methacrylate has been copolymerized with hydrophilic monomer methacrylic acid in aqueous solution without any additional emulsifier used via a two-step polymerization process of raft. the ftir and gpc results indicated that amphiphilic copolymers with a narrow molecular weight distribution and well-defined blocks have been synthesized successfully. and the copolymers are likely to form steady micelles in the emulsion. indicated by tem, it is clear that micelles with a diameter of 70-120 rim have been formed. despite a content of 22 wt% of hydrophilic carboxyl, films formed by casting the emulsion onto the baseplate can be hydrophobic after heating treatment. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | CHAIN TRANSFER AGENT ; BLOCK-COPOLYMERS ; ACRYLIC-ACID ; COMPLEXES ; ARCHITECTURES ; STYRENE ; LATEX |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000253322100008 |
| 出版者 | ELSEVIER SCIENCE SA |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2386709 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Weiqu |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Shouping,Liu, Weiqu. Synthesis and surface characterization of an amphiphilic fluorinated copolymer via emulsifier-free emulsion polymerization of raft[J]. Journal of fluorine chemistry,2008,129(2):125-130. |
| APA | Xu, Shouping,&Liu, Weiqu.(2008).Synthesis and surface characterization of an amphiphilic fluorinated copolymer via emulsifier-free emulsion polymerization of raft.Journal of fluorine chemistry,129(2),125-130. |
| MLA | Xu, Shouping,et al."Synthesis and surface characterization of an amphiphilic fluorinated copolymer via emulsifier-free emulsion polymerization of raft".Journal of fluorine chemistry 129.2(2008):125-130. |
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来源：中国科学院大学
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