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Electroluminescence from singlet excited-state of the exciplex between (2,3-dicarbonitrilopyrazino[2,3-f][1,10]phenanthroline)re(co)(3)cl and cbp

文献类型:期刊论文

作者Si, Zhenjun1,2; Li, Jiang3; Li, Bin1; Hong, Ziruo1; Liu, Shiyong3; Li, Wenlian1
刊名Journal of physical chemistry c
出版日期2008-03-13
卷号112期号:10页码:3920-3925
ISSN号1932-7447
DOI10.1021/jp075621u
通讯作者Li, bin(lib020@ciomp.ac.cn)
英文摘要(2,3-dicarbonitrilopyrazino[2,3-f] [1,10]phenanthroline)re(co)(3)cl (dicnpp-re) is synthesized successfully, and the photophysics, the electrochemistry, and the thermogravimetric analysis are performed to study the properties of dicnpp-re. it is found that the exciplex with lambda(max) at similar to 620 nm can be formed between cbp and dicnpp-re, and the exciplex emission is confirmed to be from the singlet excited state of the bound cbp and dicnpp-re molecules by the measurement of the lifetime of the cbp/dicnpp-re film. color-tunable el devices based on a host material of cbp and a dopant material of dicnpp-re are fabricated. a cbp/dicnpp-re (3%) based el device emits white light with cie coordinates of (x = 0.35, y = 0.32). the spectrum consists of three discrete bands centered at 380 nm from cbp, 560 nm from the characteristic (mlct)-m-3 state of dicnpp-re, and 620 nm from the exciplex between dicnpp-re and cbp. when the doping concentration is 16%, the el spectrum mainly demonstrates the red exciplex emission with cie coordinates of (x = 0.57, y = 0.33).
WOS关键词LIGHT-EMITTING-DIODES ; RHENIUM(I) COMPLEXES ; EMISSION ; DEVICES ; LIGANDS
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000253784400064
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2387360
专题中国科学院大学
通讯作者Li, Bin
作者单位1.Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
2.Chinese Acad Sci, Grad Sch, Changchun 130033, Peoples R China
3.Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130023, Peoples R China
推荐引用方式
GB/T 7714
Si, Zhenjun,Li, Jiang,Li, Bin,et al. Electroluminescence from singlet excited-state of the exciplex between (2,3-dicarbonitrilopyrazino[2,3-f][1,10]phenanthroline)re(co)(3)cl and cbp[J]. Journal of physical chemistry c,2008,112(10):3920-3925.
APA Si, Zhenjun,Li, Jiang,Li, Bin,Hong, Ziruo,Liu, Shiyong,&Li, Wenlian.(2008).Electroluminescence from singlet excited-state of the exciplex between (2,3-dicarbonitrilopyrazino[2,3-f][1,10]phenanthroline)re(co)(3)cl and cbp.Journal of physical chemistry c,112(10),3920-3925.
MLA Si, Zhenjun,et al."Electroluminescence from singlet excited-state of the exciplex between (2,3-dicarbonitrilopyrazino[2,3-f][1,10]phenanthroline)re(co)(3)cl and cbp".Journal of physical chemistry c 112.10(2008):3920-3925.

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来源:中国科学院大学

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