Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts
文献类型：期刊论文
| 作者 | Guan, Yejun; Li, Ying; van Santen, Rutger A.; Hensen, Emiel J. M.; Li, Can |
| 刊名 | catalysis letters
 |
| 出版日期 | 2007-08-01 |
| 卷号 | 117期号:1-2页码:18-24 |
| 关键词 | SBA-15 iron ethanol dehydrogenation dehydration |
| 产权排序 | 1;1 |
| 通讯作者 | 关业军 ; ying li ; rutger a. van santen ; emiel j. m. |
| 英文摘要 | the iron location in fesba- 15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. at low iron loading, fe is present as isolated fe3+ species in the amorphous silica phase. at higher loading additional aggregated forms of iron oxide exist. isolated fe3+ species in the silica matrix imply bronsted acidity resulting in selective formation of ethylene, whereas feox clusters catalyze formation of ethylene and aldehyde. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | mesoporous materials ; selective oxidation ; copper-catalysts ; zinc-oxide ; ethanol ; silica ; iron ; fe-sba-15 ; aluminum ; ethylene |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000248824200002 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103005]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China 2.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands |
| 推荐引用方式 GB/T 7714 | Guan, Yejun,Li, Ying,van Santen, Rutger A.,et al. Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts[J]. catalysis letters,2007,117(1-2):18-24. |
| APA | Guan, Yejun,Li, Ying,van Santen, Rutger A.,Hensen, Emiel J. M.,&Li, Can.(2007).Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts.catalysis letters,117(1-2),18-24. |
| MLA | Guan, Yejun,et al."Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts".catalysis letters 117.1-2(2007):18-24. |
入库方式： OAI收割
来源：大连化学物理研究所
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