Catalytic applications of sulfonic acid functionalized mesoporous organosilicas with different fraction of organic groups in the pore wall
文献类型：期刊论文
| 作者 | Liu, Jian; Yang, Jie; Li, Congming; Yang, Qihua |
| 刊名 | journal of porous materials
 |
| 出版日期 | 2009-06-01 |
| 卷号 | 16期号:3页码:273-281 |
| 关键词 | Periodic mesoporous organosilicas Organosulfonic acid Functionalized Solid acids Catalysis |
| 产权排序 | （1;1） |
| 通讯作者 | 杨启华 |
| 英文摘要 | organosulfonic acid functionalized mesoporous organosilicas with different fraction of organic groups in the pore wall was synthesized in the presence of p123 (eo(20)po(70)eo(20)) by controlling the molar ratio of tetramethoxysilane (tmos) to 1,2-bis(trimethoxysilyl)ethane (btme) in the initial mixture during the co-condensation process of silane precursors in acidic medium. structural characterizations (x-ray diffraction, nitrogen sorption analysis, and transmission electron microscopy) show that all materials have ordered hexagonal mesoporous structure with large pore diameter (7-9 nm). the existence of ethane and sulfonic acid groups in the material was verified by (29)si mas and (13)c cp mas nmr and x-ray photoelectron spectroscopy (xps). the mesoporous solid acids can adsorb both water and hexane (the adsorption capacity for water and hexane is 240 and 600 mg/g, respectively) due to the existence of surface hydroxyl groups, propyl sulfonic acid group, and the ethane moiety. these mesoporous solid acids are efficient catalysts for the dehydration of 1-butanol and the hydration of propylene oxide (po). |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | inorganic hybrid materials ; heterogeneous catalysts ; mcm-41-type silica ; benzene-silica ; combined alkyl ; fatty-acid ; esterification ; sba-15 ; frameworks ; design |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000265537800006 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103033]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jian,Yang, Jie,Li, Congming,et al. Catalytic applications of sulfonic acid functionalized mesoporous organosilicas with different fraction of organic groups in the pore wall[J]. journal of porous materials,2009,16(3):273-281. |
| APA | Liu, Jian,Yang, Jie,Li, Congming,&Yang, Qihua.(2009).Catalytic applications of sulfonic acid functionalized mesoporous organosilicas with different fraction of organic groups in the pore wall.journal of porous materials,16(3),273-281. |
| MLA | Liu, Jian,et al."Catalytic applications of sulfonic acid functionalized mesoporous organosilicas with different fraction of organic groups in the pore wall".journal of porous materials 16.3(2009):273-281. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。