Synthesis and optical properties of two novel chlorobismuthate(iii) complexes: [8-hydroxyquinolinium](4)k-2[bicl6](2)center dot 6h(2)o (1) and [8-hydroxyquinolinium](6)[bi2cl10][bicl5(h2o)]center dot 6h(2)o (2)
文献类型：期刊论文
| 作者 | Wang, Yong-Jing1,2; Xu, Li1 |
| 刊名 | Journal of molecular structure
 |
| 出版日期 | 2008-03-17 |
| 卷号 | 875期号:1-3页码:570-576 |
| 关键词 | Chlorobismuthate(iii) complex Crystal structure Photoluminescence |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2007.06.003 |
| 通讯作者 | Xu, li() |
| 英文摘要 | Two novel chlorobismuthate(iii) complexes [8-hydroxyquinolinium](4)k-2[bicl6](2)center dot 6h(2)o (1) and [8-hydroxyquinolinium](6)[bi2cl10] [bicl5(h2o)]center dot 6h(2)o (2) have been synthesized in solution and characterized by single-crystal x-ray diffraction. the structure of 1 contains 1-d inorganic zigzag chains formed by bicl6 octahedra and kcl4o3 decahedra with organic 8-hydroxyquinolinium cations binding through k-o bonds or h-bonds. and compound 2 has two different anionic units of [bi2cl10](4-) and [bicl5(h2o)](2-). ir, uv-vis dris, and fluorescent spectra of two compounds were studied. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | X-RAY-DIFFRACTION ; CRYSTAL-STRUCTURES ; STRETCHING FREQUENCIES ; VIBRATIONAL-SPECTRA ; PHASE-TRANSITIONS ; CHLOROANTIMONATES(III) ; PENTACHLOROANTIMONATE ; 8-HYDROXYQUINOLINE ; 4,4'-BIPYRIDINIUM ; (C10H8N2H2)SBCL5 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000254765700076 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2387666 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Li |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yong-Jing,Xu, Li. Synthesis and optical properties of two novel chlorobismuthate(iii) complexes: [8-hydroxyquinolinium](4)k-2[bicl6](2)center dot 6h(2)o (1) and [8-hydroxyquinolinium](6)[bi2cl10][bicl5(h2o)]center dot 6h(2)o (2)[J]. Journal of molecular structure,2008,875(1-3):570-576. |
| APA | Wang, Yong-Jing,&Xu, Li.(2008).Synthesis and optical properties of two novel chlorobismuthate(iii) complexes: [8-hydroxyquinolinium](4)k-2[bicl6](2)center dot 6h(2)o (1) and [8-hydroxyquinolinium](6)[bi2cl10][bicl5(h2o)]center dot 6h(2)o (2).Journal of molecular structure,875(1-3),570-576. |
| MLA | Wang, Yong-Jing,et al."Synthesis and optical properties of two novel chlorobismuthate(iii) complexes: [8-hydroxyquinolinium](4)k-2[bicl6](2)center dot 6h(2)o (1) and [8-hydroxyquinolinium](6)[bi2cl10][bicl5(h2o)]center dot 6h(2)o (2)".Journal of molecular structure 875.1-3(2008):570-576. |
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来源：中国科学院大学
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