Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine)
文献类型：期刊论文
| 作者 | Zhao Jun1,2; Xu Li1 |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:6页码:687-690 |
| 关键词 | Molybdenum Mixed-ligand Hydrogen bonds Crystal structure |
| ISSN号 | 0254-5861 |
| 通讯作者 | Xu li(xli@fjirsm.ac.cn) |
| 英文摘要 | The novel mixed-ligand neutral compound mo3o4(c2o4)(2)center dot bipy(h2o)(3)]center dot etoh center dot 2h(2)o (bipy = 2,2'-bipyridine) has been prepared by the reaction of oxalic acid elution of mo(iv) and bipy, and characterized by single-crystal x-ray diffraction analysis and ir. the crystal is of triclinic, space groups p (1) over bar with a = 9.5520(2), b = 10.3730(1), c = 13.5722(2) angstrom, alpha = 74.940(12), beta = 80.772(14), gamma = 69.898(11)degrees, v = 1215.73(11) angstrom(3), z = 2, c16h24mo3n2o18, m-r = 820.19, d-c = 2.241 g/cm(3), mu = 1.616 mm(-1), f(000) = 808, t = 293(2) k, the final r = 0.0424 and wr = 0.0939 for 4119 observed reflections with i > 2 sigma(i). the trinuclear unit is coordinated by mixed ligands of oxalate and bipy. the intermolecular hydrogen bonding interactions among adjacent [mo3o4(c2o4)(2)center dot bipy(h2o)(3)] extend the compound into a three-dimensional supramolecular framework. the uncoordinated water molecules and ethal molecules act as space-fillers and consolidate the whole architecture through hydrogen bonding interactions. |
| WOS关键词 | AQUEOUS MOLYBDENUM(IV) ; ISOTOPIC OXYGEN ; SYSTEMS |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000257348000010 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2387791 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu Li |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Jun,Xu Li. Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine)[J]. Chinese journal of structural chemistry,2008,27(6):687-690. |
| APA | Zhao Jun,&Xu Li.(2008).Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine).Chinese journal of structural chemistry,27(6),687-690. |
| MLA | Zhao Jun,et al."Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine)".Chinese journal of structural chemistry 27.6(2008):687-690. |
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来源：中国科学院大学
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