Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts
文献类型：期刊论文
| 作者 | Xiang, Minglin1,2; Li, Debao1; Xiao, Haicheng1,2; Zhang, Hanli1,2; Qi, Huijie1; Li, Wenhuai1; Zhong, Bing1; Sun, Yuhan1 |
| 刊名 | Fuel
 |
| 出版日期 | 2008-04-01 |
| 卷号 | 87期号:4-5页码:599-603 |
| 关键词 | K/beta-mo2c Fischer-tropsch elements Higher alcohols synthesis |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2007.01.041 |
| 通讯作者 | Li, debao(dbli@sxicc.ac.cn) |
| 英文摘要 | Fischer-tropsch elements (fe, co and ni) modified k/beta-mo2c catalysts were prepared and investigated for their performance in co hydrogenation. the results revealed that ni or co modified k/beta-mo2c catalysts were shown to be highly active and selective towards the synthesis of mixed alcohols, especially for the c2+oh production, but fe caused a negative effect. ni or co led to a decrease in apparent activation energies for c-1-c-4 alcohols, whereas fe caused a slight increase for methanol and the decrease for c-2-c-4 alcohols. as a result, the promotion effects of fischer-tropsch elements were different and followed the sequence: ni >> co > fe for the activity and ni >> co > fe for the c2+oh alcohol selectivity. (c) 2007 published by elsevier ltd. |
| WOS关键词 | MOLYBDENUM CARBIDE CATALYSTS ; SYNTHESIS GAS ; CARBON-MONOXIDE ; MIXED ALCOHOLS ; PERFORMANCE ; HYDROGENATION ; CO |
| WOS研究方向 | Energy & Fuels ; Engineering |
| WOS类目 | Energy & Fuels ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000253332200025 |
| 出版者 | ELSEVIER SCI LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2387809 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Debao |
| 作者单位 | 1.Chinese Acad Sci, Shanxi Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Minglin,Li, Debao,Xiao, Haicheng,et al. Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts[J]. Fuel,2008,87(4-5):599-603. |
| APA | Xiang, Minglin.,Li, Debao.,Xiao, Haicheng.,Zhang, Hanli.,Qi, Huijie.,...&Sun, Yuhan.(2008).Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts.Fuel,87(4-5),599-603. |
| MLA | Xiang, Minglin,et al."Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts".Fuel 87.4-5(2008):599-603. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。