Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes
文献类型：期刊论文
| 作者 | Yin, Weili1; Chu, Changhu1; Lu, Qiongqiong1; Tao, Jianwei1; Liang, Xinmiao1,2; Liu, Renhua1 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2010 |
| 卷号 | 352期号:1页码:113-118 |
| 关键词 | aerobic oxidation iron chloride primary alcohols sodium nitrite TEMPO |
| 产权排序 | 2;5 |
| 通讯作者 | 梁鑫淼 ; 刘仁华 |
| 英文摘要 | a variety of 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (tempo) derivatives has been screened for their ability in the oxidation of primary alcohols to the aldehydes with dioxygen under mild conditions. an evaluation of the efficiency of these 4-substituted tempo derivatives in the alcohol oxidation may allow an insight into the effect of the structural variations of tempo on the oxidation of alcohols, which should facilitate catalyst design and screening efforts. based on the screening results of 4-substituted tempo derivatives, the catalyst comprised of 4-acetamido-tempo, iron chloride and sodium nitrite, has been developed for the highly efficient oxidation of a wide range of primary alcohols including primary aliphatic alcohols to the corresponding aldehydes under mild conditions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | transition-metal-free ; aqueous hydrogen-peroxide ; liquid-phase oxidation ; molecular-oxygen ; mild conditions ; selective oxidation ; benzylic alcohols ; palladium nanoparticles ; atmospheric oxygen ; ruthenium catalyst |
| 收录类别 | SCI ; IC ; CCR |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000274339500009 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103075]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, Weili,Chu, Changhu,Lu, Qiongqiong,et al. Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes[J]. advanced synthesis & catalysis,2010,352(1):113-118. |
| APA | Yin, Weili,Chu, Changhu,Lu, Qiongqiong,Tao, Jianwei,Liang, Xinmiao,&Liu, Renhua.(2010).Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes.advanced synthesis & catalysis,352(1),113-118. |
| MLA | Yin, Weili,et al."Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes".advanced synthesis & catalysis 352.1(2010):113-118. |
入库方式： OAI收割
来源：大连化学物理研究所
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