中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
High-performance all-solid-state dye-sensitized solar cells utilizing imidazolium-type ionic crystal as charge transfer layer

文献类型:期刊论文

作者Zhao, Yong1,2; Zhai, Jin1,2; He, Jinling1,2; Chen, Xiao1,2; Chen, Li1,2; Zhang, Libing1; Tian, Yuxi1,2; Jiang, Lei1; Zhu, Daoben1
刊名Chemistry of materials
出版日期2008-10-14
卷号20期号:19页码:6022-6028
ISSN号0897-4756
DOI10.1021/cm800673x
通讯作者Zhai, jin(zhaijin@iccas.ac.cn)
英文摘要An organic ionic crystal, 1-methyl-3-acetyl-imidazolium iodide (ma-ii), was synthesized and applied into all-solid-state dye-sensitized solar cells as electrolyte material. we adopted 1-methyl-3-propylimidazolium tetra-fluoroborate as a crystal growth inhibitor, lithium bis-trifluoro-methanesulfonylimide its a change transport enhancer, and 4-tert-butyl pyridine as a carrier recombination inhibitor. the solar cell devices achieved the total conversion efficiencies of 2.6 and 2.0% under half a sun and one sun irradiation, respectively, showing a good stability even without lilly sealing and protection from ambient condition. the inner work mechanism of solar cell devices was analyzed by measuring the photovoltage, photocurrent transients, and the electrochemical impedance spectra. the results indicated that target solid-state materials from liquid molten salts can be obtained ultimately through molecular design and adjustments of molecular structure, which can be used effectively in photoelectrical devices.
WOS关键词NANOCRYSTALLINE TIO2 ; RECOMBINATION KINETICS ; INTERFACIAL PROPERTIES ; ELECTRICAL-IMPEDANCE ; PHOTOVOLTAIC DEVICE ; LIQUID ELECTROLYTE ; HOLE CONDUCTORS ; GEL ELECTROLYTE ; EFFICIENCY ; CONVERSION
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000259871500013
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2388025
专题中国科学院大学
通讯作者Zhai, Jin
作者单位1.BNLMS, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Yong,Zhai, Jin,He, Jinling,et al. High-performance all-solid-state dye-sensitized solar cells utilizing imidazolium-type ionic crystal as charge transfer layer[J]. Chemistry of materials,2008,20(19):6022-6028.
APA Zhao, Yong.,Zhai, Jin.,He, Jinling.,Chen, Xiao.,Chen, Li.,...&Zhu, Daoben.(2008).High-performance all-solid-state dye-sensitized solar cells utilizing imidazolium-type ionic crystal as charge transfer layer.Chemistry of materials,20(19),6022-6028.
MLA Zhao, Yong,et al."High-performance all-solid-state dye-sensitized solar cells utilizing imidazolium-type ionic crystal as charge transfer layer".Chemistry of materials 20.19(2008):6022-6028.

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来源:中国科学院大学

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