Transesterification of dimethyl carbonate with phenol over a bimetallic molybdenum and copper catalyst
文献类型：期刊论文
| 作者 | Tong, Dongshen1,2; Chen, Tong1; Ma, Fei1; Kang, Tao1; Lei, Yongeheng1; Hu, Jing1; Wang, Yue1; Wang, Gongying1 |
| 刊名 | Reaction kinetics and catalysis letters
 |
| 出版日期 | 2008 |
| 卷号 | 94期号:1页码:121-129 |
| 关键词 | Phenol Dimethyl carbonate Transesterification Mo-cu bimetallic oxides |
| ISSN号 | 0133-1736 |
| DOI | 10.1007/s11144-008-5272-z |
| 通讯作者 | Wang, gongying(gywang@cioc.ac.cn) |
| 英文摘要 | Mo-cu bimetallic oxides were found to be efficient heterogeneous catalysts for the transesterification of dimethyl carbonate (dmc) with phenol. when the reaction was carried out between 150 and 180 degrees c, with a molar of mo/cu of 1:1, molar ratio of phenol/dmc of 1:1, 4.8 wt.% of the catalyst, 9 h, the conversion of phenol was 49.9%, and the total yield of mpc and dpc was 45.4%. catalyst reuse showed a gradual decline in the catalytic activity. the decrease in catalytic activity might be due to leaching out of mo and cu, and/or carbon deposition. |
| WOS关键词 | DIPHENYL CARBONATE ; DIALKYL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000257052300016 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2388154 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Gongying |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 10039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Dongshen,Chen, Tong,Ma, Fei,et al. Transesterification of dimethyl carbonate with phenol over a bimetallic molybdenum and copper catalyst[J]. Reaction kinetics and catalysis letters,2008,94(1):121-129. |
| APA | Tong, Dongshen.,Chen, Tong.,Ma, Fei.,Kang, Tao.,Lei, Yongeheng.,...&Wang, Gongying.(2008).Transesterification of dimethyl carbonate with phenol over a bimetallic molybdenum and copper catalyst.Reaction kinetics and catalysis letters,94(1),121-129. |
| MLA | Tong, Dongshen,et al."Transesterification of dimethyl carbonate with phenol over a bimetallic molybdenum and copper catalyst".Reaction kinetics and catalysis letters 94.1(2008):121-129. |
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来源：中国科学院大学
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