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Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries
文献类型：期刊论文
| 作者 | Lian, Peichao1; Zhu, Xuefeng2; Liang, Shuzhao1; Li, Zhong1; Yang, Weishen2; Wang, Haihui1 |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2010-04-30 |
| 卷号 | 55期号:12页码:3909-3914 |
| 关键词 | Lithium-ion batteries Graphite oxide Thermal exfoliation Graphene sheets |
| 产权排序 | 2;2 |
| 通讯作者 | haihui wang |
| 英文摘要 | high quality graphene sheets were prepared from graphite powder through oxidation followed by rapid thermal expansion in nitrogen atmosphere. the preparation process was systematically investigated by x-ray diffraction (xrd), fourier transform infrared spectroscopy (ftir), raman spectroscopy and brunauer-emmett-teller (bet) measurements. the morphology and structure of graphene sheets were characterized by scanning electron microscope (sem) and high-resolution transmission electron microscopy (hrtem). the electrochemical performances were evaluated in coin-type cells versus metallic lithium. it is found that the graphene sheets possess a curled morphology consisting of a thin wrinkled paper-like structure, fewer layers (similar to 4 layers) and large specific surface area (492.5 m(2) g(-1)). the first reversible specific capacity of the prepared graphene sheets was as high as 1264 ma h g(-1) at a current density of 100 ma g(-1). even at a high current density of 500 ma g(-1), the reversible specific capacity remained at 718 ma h g(-1). after 40 cycles, the reversible capacity was still kept at 848 ma h g(-1) at the current density of 100 ma g(-1). these results indicate that the prepared high quality graphene sheets possess excellent electrochemical performances for lithium storage. (c) 2010 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | graphite oxide ; electrochemical performance ; carbon nanotubes ; electrode materials ; raman-spectra ; li storage ; nanosheets ; insertion ; oxidation ; cokes |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000277498000010 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103137]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Beijing 100864, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lian, Peichao,Zhu, Xuefeng,Liang, Shuzhao,et al. Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries[J]. electrochimica acta,2010,55(12):3909-3914. |
| APA | Lian, Peichao,Zhu, Xuefeng,Liang, Shuzhao,Li, Zhong,Yang, Weishen,&Wang, Haihui.(2010).Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries.electrochimica acta,55(12),3909-3914. |
| MLA | Lian, Peichao,et al."Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries".electrochimica acta 55.12(2010):3909-3914. |
入库方式： OAI收割
来源：大连化学物理研究所
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