Oxygen permeation and partial oxidation of methane in dual-phase membrane reactors
文献类型：期刊论文
| 作者 | Zhu, Xuefeng; Li, Qiming; He, Yufeng; Cong, You; Yang, Weishen |
| 刊名 | journal of membrane science
 |
| 出版日期 | 2010-09-15 |
| 卷号 | 360期号:1-2页码:454-460 |
| 关键词 | Dual-phase membrane Oxygen permeation POM Membrane reactor Mixed conductor |
| 产权排序 | 1;1 |
| 通讯作者 | 杨维慎 |
| 英文摘要 | oxygen permeation and partial oxidation of methane (pom) were investigated in 75 wt.% ce(0.85)sm(0.15) o(1.925)-25 wt.% sm(0.6)sr(0.4)feo(3-delta) (sdc-ssf) dual-phase composite membrane reactors. the dual-phase membrane prepared via a one-pot method comprises a fluorite-type oxide ionic conductor (sdc) for the transport of oxide ions and a perovskite-type mixed conductor (ssf) for the transport of both oxide ions and electrons. x-ray diffraction (xrd) results reveal good phase compatibility between the fluorite and perovskite oxides even after sintered at high temperature. the oxygen permeation flux increased with time in the initial stage, from 0.23 to 0.5 cm(3) cm(-2) min(-1) in the first 18 h. once a steady state was reached, the permeation flux remained constant in the investigated period (> 500 h). long-term operation of pom reaction was successfully achieved in dual-phase membrane reactors, and methane conversion and co selectivity >98% were obtained for pure methane as the feed. xrd, scanning electron microscope (sem) and energy dispersive x-ray spectroscopy (edx) characterizations reveal good structural stability for the dual-phase membrane, even after long-term operation under syngas production conditions. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | engineering, chemical ; polymer science |
| 研究领域[WOS] | engineering ; polymer science |
| 关键词[WOS] | dense ceramic membranes ; hollow-fiber membranes ; composite membranes ; structural stability ; synthesis gas ; perovskite ; syngas ; permeability ; transport ; conductivity |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000280311500052 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103145]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Xuefeng,Li, Qiming,He, Yufeng,et al. Oxygen permeation and partial oxidation of methane in dual-phase membrane reactors[J]. journal of membrane science,2010,360(1-2):454-460. |
| APA | Zhu, Xuefeng,Li, Qiming,He, Yufeng,Cong, You,&Yang, Weishen.(2010).Oxygen permeation and partial oxidation of methane in dual-phase membrane reactors.journal of membrane science,360(1-2),454-460. |
| MLA | Zhu, Xuefeng,et al."Oxygen permeation and partial oxidation of methane in dual-phase membrane reactors".journal of membrane science 360.1-2(2010):454-460. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。