Crystal structure and charge transfer energy of the vaterite-type orthoborate ybo(3): eu
文献类型:期刊论文
作者 | Li, Ling1,2; Zhou, Shihong1; Zhang, Siyuan1 |
刊名 | Solid state sciences
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出版日期 | 2008-09-01 |
卷号 | 10期号:9页码:1173-1178 |
关键词 | Charge transfer energy Ybo(3): eu Crystal structure |
ISSN号 | 1293-2558 |
DOI | 10.1016/j.solidstatesciences.2007.12.023 |
通讯作者 | Zhang, siyuan(syzhang@ciac.jl.cn) |
英文摘要 | Ligand-to-metal charge transfer energies of ybo(3):eu have been investigated from the chemical bond viewpoint. the chemical bond parameters, such as the covalency, the polarizability of the chemical bond volume, and the presented charge of the ligands in the chemical bond have been quantitatively determined based on the dielectric theory of complex crystal. we calculated the environmental factor (h(e)), which is the major factor influencing the charge transfer energy in the compounds. the calculated results show that the suitable group space of ybo(3) is c2/c. the method provides us with a supplementary tool to judge the proper structure when the structure of the crystal has many uncertain space groups. (c) 2007 elsevier masson sas. all rights reserved. |
WOS关键词 | CHEMICAL-BOND ANALYSIS ; LUMINESCENT PROPERTIES ; PHOTOLUMINESCENCE PROPERTIES ; PHASE-TRANSITION ; TRANSFER SPECTRA ; OXIDES ; NANOCRYSTALS ; BAND ; EU3 ; NONLINEARITY |
WOS研究方向 | Chemistry ; Physics |
WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Physics, Condensed Matter |
语种 | 英语 |
WOS记录号 | WOS:000259683900010 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2388373 |
专题 | 中国科学院大学 |
通讯作者 | Zhang, Siyuan |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Ling,Zhou, Shihong,Zhang, Siyuan. Crystal structure and charge transfer energy of the vaterite-type orthoborate ybo(3): eu[J]. Solid state sciences,2008,10(9):1173-1178. |
APA | Li, Ling,Zhou, Shihong,&Zhang, Siyuan.(2008).Crystal structure and charge transfer energy of the vaterite-type orthoborate ybo(3): eu.Solid state sciences,10(9),1173-1178. |
MLA | Li, Ling,et al."Crystal structure and charge transfer energy of the vaterite-type orthoborate ybo(3): eu".Solid state sciences 10.9(2008):1173-1178. |
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来源:中国科学院大学
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