Tunable Assembly of Organosilica Hollow Nanospheres
文献类型：期刊论文
| 作者 | Liu, Jian1; Bai, Shiyang1,2; Zhong, Hua1; Li, Can1; Yang, Qihua1 |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2010-01-21 |
| 卷号 | 114期号:2页码:953-961 |
| 产权排序 | 1;1 |
| 通讯作者 | 李灿 ; 杨启华 |
| 英文摘要 | hollow nanospheres with a particle size of less than 25 nm have been successfully fabricated using all ethylene-, phenylene-, and 1,4-diethylphenylene-bridging silane precursor with f127 as a soft template under an acidic medium. as the size and flexibility of the bridging organic group increases, it is more and more difficult for the formation of hollow nanospheres. the organic additive, 1,3,5-trimethylbenzene, could finely tune the particle size of the nanosphere from 12 to 25 nm. it was found that silane precursors with hydrophobicity and slow hydrolysis rate favor the formation of hollow nanospheres and hydrophilic silane precursors such as tetra methoxysilane induce the formation of mesostructured bulk materials. under the current synthesis conditions, carefully tuning the interaction between templates and silica species, organosilica hollow nanospheres with controlled composition call be successfully obtained. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | periodic mesoporous organosilicas ; molecular-scale ; large pores ; silica ; wall ; surfactant ; spheres ; shell ; nanoparticles ; organization |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000273400400037 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103179]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jian,Bai, Shiyang,Zhong, Hua,et al. Tunable Assembly of Organosilica Hollow Nanospheres[J]. journal of physical chemistry c,2010,114(2):953-961. |
| APA | Liu, Jian,Bai, Shiyang,Zhong, Hua,Li, Can,&Yang, Qihua.(2010).Tunable Assembly of Organosilica Hollow Nanospheres.journal of physical chemistry c,114(2),953-961. |
| MLA | Liu, Jian,et al."Tunable Assembly of Organosilica Hollow Nanospheres".journal of physical chemistry c 114.2(2010):953-961. |
入库方式： OAI收割
来源：大连化学物理研究所
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