Creation of a monomeric ag species on the surface of gamma-zrp as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins
文献类型：期刊论文
| 作者 | Liu, Junhua1,2; Wang, Fang1,2; Xu, Xianlun1 |
| 刊名 | Catalysis letters
 |
| 出版日期 | 2008 |
| 卷号 | 120期号:1-2页码:106-110 |
| 关键词 | Allylic oxidation Cycloolefin Enols Silver Zirconium phosphates |
| ISSN号 | 1011-372X |
| DOI | 10.1007/s10562-007-9259-6 |
| 通讯作者 | Xu, xianlun(xlxu@lzb.ac.cn) |
| 英文摘要 | A hybrid complex zr(po4)(aghpo4) was prepared by ion-exchange and its activity was examined on the allylic oxidation of cycloolefins using tert-butylhydroperoxide (tbhp) as oxidant under argon atmosphere. under these reaction conditions, attack of the activated c-h bond was preferred instead of the epoxidation of c=c bond, yielding enols as the main products, this is a novel highly active/selective and reusable heterogeneous catalyst. |
| WOS关键词 | ZIRCONIUM PHOSPHATE ; ALLYLIC OXIDATION ; CYCLOHEXENE ; EPOXIDATION ; OLEFINS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000252160200016 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2388450 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Xianlun |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Junhua,Wang, Fang,Xu, Xianlun. Creation of a monomeric ag species on the surface of gamma-zrp as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins[J]. Catalysis letters,2008,120(1-2):106-110. |
| APA | Liu, Junhua,Wang, Fang,&Xu, Xianlun.(2008).Creation of a monomeric ag species on the surface of gamma-zrp as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins.Catalysis letters,120(1-2),106-110. |
| MLA | Liu, Junhua,et al."Creation of a monomeric ag species on the surface of gamma-zrp as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins".Catalysis letters 120.1-2(2008):106-110. |
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来源：中国科学院大学
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