Synthesis and characterization of coapo-5 with different cobalt contents and their catalytic performance for cyclohexane oxidation
文献类型：期刊论文
| 作者 | Zhao Rui-Hua1,2,3; Dong Mei1; Qin Zhang-Feng1; Ding Han-Fei1,2; Guo Xing-Cui1,2; Wang Han-Guo1 |
| 刊名 | Acta physico-chimica sinica
 |
| 出版日期 | 2008-12-01 |
| 卷号 | 24期号:12页码:2304-2308 |
| 关键词 | Aluminophosphate molecular sieves Hydrothermal synthesis Cobalt incorporation Cyclohexane oxidation Cyclohexanone |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/pku.whxb20081226 |
| 通讯作者 | Wang han-guo(iccjgw@sxicc.ac.cn) |
| 英文摘要 | Cobalt substituted molecular sieves (coapo-5) with different cobalt content were synthesized hydrothermally. the as-synthesized samples were characterized by x-ray diffraction (xrd), scanning electron microscopy (sem), ultraviolet-visible diffuse reflectance spectroscopy (uv-vis drs), thermogravimetric(tg) analysis, and inductively coupled plasma-atomic emission spectrometry (icp-aes). the results indicated that cobalt was incorporated into the framework of alpo4-5 molecular sieves and the as-synthesized coapo-5 was highly crystalline and pure. there is a good linear relationship between the crystal cell parameters and the cobalt content in coapo-5. the uv-vis intensity of co(ii) is significantly reduced through calcinations as co(ii) is oxidized to co(iii) during calcinations. the as-synthesized coapo-5 exhibited excellent performance for the oxidation of cyclohexane using molecular oxygen as oxidant. the conversion of cyclohexane and the ratio of cyclohexanol to cyclohexanone in the product increased as the cobalt content increased in coapo-5. at n(co)/n(p)=0.04 the conversion of cyclohexane was 23.3%. |
| WOS关键词 | ALUMINOPHOSPHATE MOLECULAR-SIEVES ; DIFFUSE-REFLECTANCE SPECTROSCOPY ; SELECTIVE OXIDATION ; CRYSTALLIZATION ; ZEOLITES ; CRYSTALS ; ALPO4-5 ; GROWTH ; CO2+ |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000262024900026 |
| 出版者 | PEKING UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2388476 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang Han-Guo |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Shanxi Kunming Tobacco Ltd Liabil Co, Taiyuan 030012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Rui-Hua,Dong Mei,Qin Zhang-Feng,et al. Synthesis and characterization of coapo-5 with different cobalt contents and their catalytic performance for cyclohexane oxidation[J]. Acta physico-chimica sinica,2008,24(12):2304-2308. |
| APA | Zhao Rui-Hua,Dong Mei,Qin Zhang-Feng,Ding Han-Fei,Guo Xing-Cui,&Wang Han-Guo.(2008).Synthesis and characterization of coapo-5 with different cobalt contents and their catalytic performance for cyclohexane oxidation.Acta physico-chimica sinica,24(12),2304-2308. |
| MLA | Zhao Rui-Hua,et al."Synthesis and characterization of coapo-5 with different cobalt contents and their catalytic performance for cyclohexane oxidation".Acta physico-chimica sinica 24.12(2008):2304-2308. |
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来源：中国科学院大学
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