A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols
文献类型：期刊论文
| 作者 | Shi, Ruijuan; Wang, Fei; Tana; Li, Yong; Huang, Xiumin; Shen, Wenjie |
| 刊名 | green chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:1页码:108-113 |
| 产权排序 | 1;1 |
| 通讯作者 | 申文杰 |
| 英文摘要 | la2o3-supported copper nanoparticles are sufficiently active for transfer dehydrogenation of primary aliphatic alcohols to aldehydes. when used for 1-octanol, the yield of 1-octanal can be as high as 63%. the catalyst is also highly effective for a wide variety of substrates, such as aromatic, aliphatic, and cyclic alcohols. the yield of the desired products approaches 100% and the turnover frequency is 86.5 h(-1). the synergistic effect between the basicity of la2o3 and the hydrogen spillover of cu particle contributes significantly to the extremely high activity of the cu/la2o3 catalyst for transfer dehydrogenation of primary aliphatic alcohols. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | environmentally benign oxidation ; molecular-oxygen ; heterogeneous catalysis ; selective oxidation ; ruthenium catalyst ; metal-catalysts ; surface ; copper ; hydrotalcite ; palladium |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000273576000017 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103369]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Ruijuan,Wang, Fei,Tana,et al. A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols[J]. green chemistry,2010,12(1):108-113. |
| APA | Shi, Ruijuan,Wang, Fei,Tana,Li, Yong,Huang, Xiumin,&Shen, Wenjie.(2010).A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols.green chemistry,12(1),108-113. |
| MLA | Shi, Ruijuan,et al."A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols".green chemistry 12.1(2010):108-113. |
入库方式： OAI收割
来源：大连化学物理研究所
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