Surface-functionalized Carbon Black as Catalyst for the Direct Production of Hydrogen Peroxide by the Oxidation of Hydroxylamine
文献类型：期刊论文
| 作者 | Song Wei; Li Yong; Guo Xiaohui; Li Juan; Shen Wenjie |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 28期号:5页码:693-698 |
| 关键词 | carbon black hydrogen peroxide oxidation hydroxylamine surface chemistry quinoid species |
| 产权排序 | 1;1 |
| 通讯作者 | 申文杰 |
| 英文摘要 | carbon black (cb) without micropores was functionalized by mixed acid and used to explore the surface chemistry effect on the production of hydrogen peroxide (h(2)o(2)). the cb materials were characterized by n(2) adsorption-desorption, xrd, sem, ftir, and tpd. the results of different characterization methods indicated that both the textural features and the surface chemical properties of cb were significantly modified by the acidic treatment. the catalytic performance of the modified cbs for hydroxylamine (nh(2)oh) oxidation increased with increasing the surface oxygen-containing species. the yield of h(2)o(2) approached 30% with the corresponding concentration of 73.9 mmol.l(-1) (w=0.25%) over the most promising cb catalyst, which was much superior to the results obtained on supported noble metals. correlations between catalytic activity and concentration of different surface functional groups on the cb samples confirmed that the quinonoid species might be the active species. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | in-situ generation ; activated carbons ; nonaqueous medium ; reduction ; oxygen ; dioxygen ; complexes ; chemistry ; acetate ; salt |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000278746200002 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103373]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song Wei,Li Yong,Guo Xiaohui,et al. Surface-functionalized Carbon Black as Catalyst for the Direct Production of Hydrogen Peroxide by the Oxidation of Hydroxylamine[J]. chinese journal of chemistry,2010,28(5):693-698. |
| APA | Song Wei,Li Yong,Guo Xiaohui,Li Juan,&Shen Wenjie.(2010).Surface-functionalized Carbon Black as Catalyst for the Direct Production of Hydrogen Peroxide by the Oxidation of Hydroxylamine.chinese journal of chemistry,28(5),693-698. |
| MLA | Song Wei,et al."Surface-functionalized Carbon Black as Catalyst for the Direct Production of Hydrogen Peroxide by the Oxidation of Hydroxylamine".chinese journal of chemistry 28.5(2010):693-698. |
入库方式： OAI收割
来源：大连化学物理研究所
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