Combustion synthesis of nanosized beta-sic powder on a large scale
文献类型:期刊论文
作者 | Liu, Guanghua1; Yang, Kun1; Li, Jiangtao1; Yang, Kun2; Du, Jisheng3; Hou, Xiaoyi3 |
刊名 | Journal of physical chemistry c
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出版日期 | 2008-04-24 |
卷号 | 112期号:16页码:6285-6292 |
ISSN号 | 1932-7447 |
DOI | 10.1021/jp710942m |
通讯作者 | Li, jiangtao(ljt0012@vip.sina.com) |
英文摘要 | Nanosized beta-sic powder was prepared by combustion synthesis on a large scale, which was carried out in a n-2 atmosphere with silicon powder and carbon black as the reactants. mechanical activation played an important role in enhancing the reactivity of the reactants, and a higher ball/charge weight ratio and a prolonged activation time were favorable for complete reaction. ptfe was added as a reaction promoter, which remarkably reduced the minimum activation time required for successful combustion synthesis. on the basis of experimental results and thermodynamical calculation, it is proposed that combustion synthesis of sic in n-2 includes two steps: (1) si reacts with n-2 to form si3n4, generating a lot of heat energy; (2) at higher temperatures the initially formed si3n4 decomposes, and released si reacts with carbon to produce sic. |
WOS关键词 | SILICON-CARBIDE ; HIGH-TEMPERATURE ; MECHANISM ; CARBON ; PHASE ; SHS ; ATMOSPHERE ; TOUGHNESS ; NITROGEN ; NITRIDE |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000255105000012 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2389465 |
专题 | 中国科学院大学 |
通讯作者 | Li, Jiangtao |
作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Liaoning Jiayi Met & Mineral Co Ltd, Dalian 116001, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Guanghua,Yang, Kun,Li, Jiangtao,et al. Combustion synthesis of nanosized beta-sic powder on a large scale[J]. Journal of physical chemistry c,2008,112(16):6285-6292. |
APA | Liu, Guanghua,Yang, Kun,Li, Jiangtao,Yang, Kun,Du, Jisheng,&Hou, Xiaoyi.(2008).Combustion synthesis of nanosized beta-sic powder on a large scale.Journal of physical chemistry c,112(16),6285-6292. |
MLA | Liu, Guanghua,et al."Combustion synthesis of nanosized beta-sic powder on a large scale".Journal of physical chemistry c 112.16(2008):6285-6292. |
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来源:中国科学院大学
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