中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Combustion synthesis of nanosized beta-sic powder on a large scale

文献类型:期刊论文

作者Liu, Guanghua1; Yang, Kun1; Li, Jiangtao1; Yang, Kun2; Du, Jisheng3; Hou, Xiaoyi3
刊名Journal of physical chemistry c
出版日期2008-04-24
卷号112期号:16页码:6285-6292
ISSN号1932-7447
DOI10.1021/jp710942m
通讯作者Li, jiangtao(ljt0012@vip.sina.com)
英文摘要Nanosized beta-sic powder was prepared by combustion synthesis on a large scale, which was carried out in a n-2 atmosphere with silicon powder and carbon black as the reactants. mechanical activation played an important role in enhancing the reactivity of the reactants, and a higher ball/charge weight ratio and a prolonged activation time were favorable for complete reaction. ptfe was added as a reaction promoter, which remarkably reduced the minimum activation time required for successful combustion synthesis. on the basis of experimental results and thermodynamical calculation, it is proposed that combustion synthesis of sic in n-2 includes two steps: (1) si reacts with n-2 to form si3n4, generating a lot of heat energy; (2) at higher temperatures the initially formed si3n4 decomposes, and released si reacts with carbon to produce sic.
WOS关键词SILICON-CARBIDE ; HIGH-TEMPERATURE ; MECHANISM ; CARBON ; PHASE ; SHS ; ATMOSPHERE ; TOUGHNESS ; NITROGEN ; NITRIDE
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000255105000012
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2389465
专题中国科学院大学
通讯作者Li, Jiangtao
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Liaoning Jiayi Met & Mineral Co Ltd, Dalian 116001, Peoples R China
推荐引用方式
GB/T 7714
Liu, Guanghua,Yang, Kun,Li, Jiangtao,et al. Combustion synthesis of nanosized beta-sic powder on a large scale[J]. Journal of physical chemistry c,2008,112(16):6285-6292.
APA Liu, Guanghua,Yang, Kun,Li, Jiangtao,Yang, Kun,Du, Jisheng,&Hou, Xiaoyi.(2008).Combustion synthesis of nanosized beta-sic powder on a large scale.Journal of physical chemistry c,112(16),6285-6292.
MLA Liu, Guanghua,et al."Combustion synthesis of nanosized beta-sic powder on a large scale".Journal of physical chemistry c 112.16(2008):6285-6292.

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来源:中国科学院大学

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