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Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker

文献类型:期刊论文

作者Zou, Yingping1,2,5; Sang, Guangyi1,2,5; Wan, Meixiu1,2,3,4; Tan, Songting3,4; Li, Yongfang1,2
刊名Macromolecular chemistry and physics
出版日期2008-07-21
卷号209期号:14页码:1454-1462
关键词Conducting polymers Electrochemistry Photochemistry Synthesis
ISSN号1022-1352
DOI10.1002/macp.200800083
通讯作者Li, yongfang(liyf@iccas.ac.cn)
英文摘要Three polythiophenes with 5%, 10% and 15%triphenylaminetrivinylene (tpav) as bridge linker, pt-tpav5, pt-tpav10 and pt-tpav15, were synthesized. the wittig-horner-emmons reaction and the stille method were employed to synthesize these polymers. the polythiophenes were subsequently used in bulk-heterojunction polymer solar cells (pscs) as donor materials. the polymers exhibited a striking and reversible color change after the oxidation of the polymer films. the power conversion efficiencies of the pscs based on pt-tpav5, pt-tpav10 and pt-tpav15 as donors and pcbm as acceptor were 0.17%, 0.50%, and 0.35%, respectively, under the illumination of am 1.5, 100 mw.cm(-2).
WOS关键词HETEROJUNCTION SOLAR-CELLS ; LIGHT-EMITTING-DIODES ; INTERNAL CHARGE-TRANSFER ; FIELD-EFFECT TRANSISTORS ; HYBRID SYSTEMS ; SIDE-CHAINS ; POLYMER ; VINYLENE ; ELECTROLUMINESCENCE ; BENZOTHIADIAZOLE
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000258282400006
出版者WILEY-BLACKWELL
URI标识http://www.irgrid.ac.cn/handle/1471x/2389655
专题中国科学院大学
通讯作者Li, Yongfang
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
3.Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
4.Xiangtan Univ, Inst Polymer Mat, Xiangtan 411105, Peoples R China
5.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zou, Yingping,Sang, Guangyi,Wan, Meixiu,et al. Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker[J]. Macromolecular chemistry and physics,2008,209(14):1454-1462.
APA Zou, Yingping,Sang, Guangyi,Wan, Meixiu,Tan, Songting,&Li, Yongfang.(2008).Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker.Macromolecular chemistry and physics,209(14),1454-1462.
MLA Zou, Yingping,et al."Synthesis, electrochemical and photovoltaic properties of multi-armed polythiophenes with triphenylamine trivinylene as conjugated linker".Macromolecular chemistry and physics 209.14(2008):1454-1462.

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来源:中国科学院大学

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